Enantioselective hydrogenation of ketones by iridium nanoparticles ligated with chiral secondary phosphine oxides
Phosphine oxide
Asymmetric hydrogenation
Cyclooctadiene
DOI:
10.1039/c5cy02206a
Publication Date:
2016-01-05T11:06:21Z
AUTHORS (6)
ABSTRACT
Chiral iridium nanoparticles (<bold>IrNPs</bold>) were synthesized by H<sub>2</sub>reduction of (1,5-cyclooctadiene)(methoxy)iridium(<sc>i</sc>) dimer ([Ir(OMe)(COD)]<sub>2</sub>) in the presence an asymmetric secondary phosphine oxide.
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