Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields

• DOI: 10.1039/c5ta04923g
• Publication Date: 2015-09-09T16:30:19Z
• Authors: L. Garzón-Tovar; A. Carné-Sánchez; C. Carbonell; I. Imaz; D. Maspoch
• Keywords: Metal organic framework; Metalorganic frameworks (MOFs); Synthetic methods; BET surface area; Reaction parameters; Space time yield; 02 engineering and technology; Reagent concentration; Water based synthesis; 0210 nano-technology

The stepwise optimisation of the room temperature, water-based synthesis of several porous CPO-27/MOF-74 materials allows fabricating them with BET surfaces areas up to 1603 m2 g−1 and space-time-yields as high as 18 720 kg m−3 per day.