Enhanced single-ion magnetic and ferroelectric properties of mononuclear Dy(iii) enantiomeric pairs through the coordination role of chiral ligands

• DOI: 10.1039/c7cc01042g
• Publication Date: 2017-03-16T11:54:19Z
• Authors: Xi-Li Li; Ming Hu; Zhigang Yin; Cancan Zhu; Cai-Ming Liu; Hong-Ping Xiao; Shaoming Fang
• Keywords: 7. Clean energy; 01 natural sciences; 3. Good health; 0104 chemical sciences

The structures and properties of two mononuclear Dy(iii) enantiomeric pairs were dramatically controlled by crystallization temperature; the pair with coordinated chiral N,N'-donor ligands exhibits enhanced single-ion magnetic, ferroelectric chiroptical respect to other one protonated ligands.