Positional immobilization of Pd nanoparticles and enzymes in hierarchical yolk–shell@shell nanoreactors for tandem catalysis

• DOI: 10.1039/c7cc03177g
• Publication Date: 2017-06-16T14:33:57Z
• Authors: Xiaoming Zhang; Lingyan Jing; Fangfang Chang; Shuai Chen; Hengquan Yang; Qihua Yang
• Keywords: Nanoreactor; Kinetic resolution; Tandem; Cascade reaction; Biocatalysis; Bifunctional catalyst

A hierarchical yolk–shell@shell nanoreactor that spatially positioned Pd nanoparticles and the CALB enzyme in separated domains is constructed, served as an efficient bifunctional catalyst for one-pot dynamic kinetic resolution (DKR) reaction of 1-phenylethylamine with excellent activity selectivity.