Functionalised cyclodextrin-based metal–organic frameworks

• DOI: 10.1039/c7cc03345a
• Publication Date: 2017-06-13T10:55:01Z
• Authors: K. J. Hartlieb; A. W. Peters; T. C. Wang; P. Deria; O. K. Farha; J. T. Hupp; J. F. Stoddart
• Keywords: 02 engineering and technology; 0210 nano-technology

CD-MOF, an extended framework incorporating the C8 symmetric cyclic oligosaccharide, γ-cyclodextrin (γ-CD), is based on coordination of alkali metal cations to alternating α-1,4-linked d-glucopyranosyl units primary and secondary faces γ-CD tori. Here, we report synthesis characterisation amino-functionalised CD-MOF that isostructural with pristine adsorbs CO2 permanently.