A mononuclear manganese(iii)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

• DOI: 10.1039/c7cc09492b
• Publication Date: 2018-01-08T14:36:58Z
• Authors: Muniyandi Sankara...; Yong-Min Lee; So Hyun Jeon; Mi Sook Seo; Kyung-Bin Cho; Wonwoo Nam
• Keywords: Reactivity

A manganese(<sc>iii</sc>)–peroxo complex was synthesized by activating dioxygen (O₂) and the amphoteric reactivity of a manganese(<sc>iii</sc>)–hydroperoxo demonstrated in electrophilic nucleophilic reactions.