Palladium-catalyzed sequential three-component reactions to access vinylsilanes

• DOI: 10.1039/c8cc05254a
• Publication Date: 2018-08-28T07:56:38Z
• Authors: Bo Zhou; Ailan Lu; Changdong Shao; Xinda Liang; Yanghui Zhang
• Keywords: Component (thermodynamics)

A palladium-catalyzed sequential three-component reaction has been developed. The palladacycles, generated through cascade reactions of aryl halides and alkynes, are the key intermediates react with hexamethyldisilane to form disilylated products. represents a useful preparative method for vinylsilanes, vinylsilanes can be transformed into tetrasubstituted alkenes.