Transition metal substituted sandwich-type polyoxometalates with a strong metal–C (imidazole) bond as anticancer agents
Imidazole
Polyoxometalate
DOI:
10.1039/c8cc07884j
Publication Date:
2018-12-21T01:04:23Z
AUTHORS (8)
ABSTRACT
The metal–carbon bond plays a pivotal role in the structural stabilities and biological activities of metal-based anticancer drugs. strong M–C<sub>imi</sub> is first introduced into sandwich-type POMs [Na<sub>0.7</sub>M<sub>5.3</sub>(H<sub>2</sub>O)<sub>2</sub>(imi)<sub>2</sub>(Himi)(SbW<sub>9</sub>O<sub>33</sub>)<sub>2</sub>]<sup>6−</sup>, (M = Ni<sup>II</sup> (<bold>1</bold>), Co<sup>II</sup> (<bold>2</bold>), imi imidazole).
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