Substituent-controlled, mild oxidative fluorination of iodoarenes: synthesis and structural study of aryl I(iii)- and I(v)-fluorides

• DOI: 10.1039/c9sc02162k
• Publication Date: 2019-06-05T14:04:20Z
• Authors: Joel Häfliger; Cody Ross Pitts; Dustin Bornemann; Roland Käser; Nico Santschi; Julie Charpentier; Elisabeth Otth; Nils Trapp; René Verel; Hans Peter Lüthi; Antonio Togni
• Keywords: Chemistry; 540; 01 natural sciences; 0104 chemical sciences

This mild TCICA/KF oxidative fluorination approach provides controllable access to aryl-IF2and aryl-IF4compounds, thus allowing detailed structural studies.