Valence tautomerism in a cobalt-verdazyl coordination compound

• DOI: 10.1039/d0cc01770a
• Publication Date: 2020-03-26T18:42:42Z
• Authors: Connor Fleming; Dorothy Chung; Servando Ponce; David J. R. Brook; Jeffrey DaRos; Raja Das; Andrew Ozarowski; Sebastian A. Stoian
• Keywords: 01 natural sciences; 0104 chemical sciences

A cobalt bis(verdazyl) compound provides a new example of valence tautomerism in acetonitrile solution though the molecule is trapped in the ‘high energy’ tautomer in the crystalline material.