Theoretical insights into non-oxidative propane dehydrogenation over Fe3C

13. Climate action 01 natural sciences 7. Clean energy 0104 chemical sciences
DOI: 10.1039/d0cp04669h Publication Date: 2020-12-18T01:15:22Z
ABSTRACT
Identifying catalysts for non-oxidative propane dehydrogenation (PDH) has become increasingly important. We show with DFT that Fe3C is selective for PDH because surface carbon atoms disrupt iron ensembles that promote competing cracking reactions.
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