Acyclic diaminocarbene-based Thiele, Chichibabin, and Müller hydrocarbons

• DOI: 10.1039/d0sc03622f
• Publication Date: 2020-10-02T06:23:32Z
• Authors: Avijit Maiti; Shubhadeep Chandra; Biprajit Sarkar; Anukul Jana
• Keywords: Chemistry; 01 natural sciences; 0104 chemical sciences

We report the synthesis of acyclic diaminocarbene (ADC)-scaffold based Thiele, Chichibabin, and Müller hydrocarbons. Studies support that singlet-triplet energy gap depends on π-conjugated spacer between ADC scaffolds.