Tethered photocatalyst-directed palladium-catalysed C–H allenylation of N-aryl tetrahydroisoquinolines
Photoredox catalysis
DOI:
10.1039/d2cc01064j
Publication Date:
2022-03-09T22:41:06Z
AUTHORS (3)
ABSTRACT
Harnessing radical intermediates in regioselective reactions presents a substantial challenge. Here, we report novel control strategy through engineering covalently tethered transition metal-photocatalysts that conjoin Pd-phosphine and Ru/Ir photoredox units. This allows us to override the innate regioselectivity of Pd-catalysed C-H allenylation N-aryl tetrahydroisoquinolines.
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