Stepwise assembly of heterometallic, heteroleptic “triblock Janus-type” metal–organic polyhedra

• DOI: 10.1039/d2cc06815j
• Publication Date: 2023-02-13T12:21:38Z
• Authors: Cornelia von Baec...; Sara Ruiz-Relaño; Inhar Imaz; Marcel Handke; Judith Juanhuix; Felipe Gándara; Arnau Carné-Sanchez; Daniel Maspoch
• Keywords: Chemistry; 01 natural sciences; 0104 chemical sciences

We present a novel strategy to assemble diverse metal ions and organic linkers into metal–organic polyhedra (MOPs). It involves use of a pre-assembled complex of a parent MOP to replicate this cage with a multicomponent character.