In situ rapid synthesis of ionic liquid/ionic covalent organic framework composites for CO2 fixation

• DOI: 10.1039/d3cc04763f
• Publication Date: 2023-11-13T08:41:13Z
• Authors: Zhifeng Xu; Wenting Wang; Bowei Chen; Haitao Zhou; Qiufang Yao; Xianjie Shen; Yuchen Pan; Dongxian Wu; Yongyong Cao; Zhangfeng Shen; Yanan Liu; Qineng Xia; Xi Li; Xiaoqin Zou; Yangang Wang; Lingchang Jiang

IL/ICOF composites were in situ synthesized via a one-pot route half an hour under ambient conditions for catalytic cycloaddition of CO2 with epoxides into cyclic carbonates. The prepared feature decent adsorption capacity 1.63 mmol g-1 at 273 K and 1 bar exhibit excellent performance terms yield durability. This work may pave new way to design construct functionalized porous organic frameworks as heterogeneous catalysts capture conversion.