Solvent-dependent valence tautomerism and polarization switching in a heterodinuclear [CrCo] complex

• DOI: 10.1039/d4qi00836g
• Publication Date: 2024-05-17T06:01:51Z
• Authors: Wenwei Zheng; Xiaopeng Zhang; Qirui Shui; Tatsuki Fukuyama; Wen-huang Xu; Yu-bo Huang; Tianchi Ji; Ziqi Zhou; Mikoto Uematsu; Sheng-Qun Su; Shinji Kanegawa; Shu-Qi Wu; Osamu Sato
• Keywords: Enantiopure drug

A stepwise synthetic approach improves the purity of heterometallic dinuclear complexes with enantiopure ligands, facilitating chemical control polarization-switching behavior in [CrCo] crystals VT transition.