Unusual solvent-regulated inversion of a metal stereocenter in an enantiopure Eu2L4 helicate: a new strategy for CPL inversion

• DOI: 10.1039/d4qi02276a
• Publication Date: 2024-10-05T06:02:23Z
• Authors: Qing Ma; Sen Yin; Ziye Song; Ting Gao; Pengfei Yan; Yanyan Zhou; Hongfeng Li
• Keywords: Enantiopure drug; Stereocenter

Developing artificial metal helicates with stimuli-responsive helicity inversion is a significant challenge in functional supramolecular chemistry. However, most reported inversions are based on the synchronous transformation of P/M conformation...