Chalcogenide-centered Cu11 clusters heteroleptically passivated by dichalcogenolates and iodo ligands

• DOI: 10.1039/d5nj01571e
• Publication Date: 2025-05-21T12:21:24Z
• Authors: Rhone P. Brocha S...; Yu-Te Kuo; Tzu-Hao Chiu; Michael N. Pillay; C. W. Liu
• Keywords: Chalcogen

Halide ligands can serve as auxiliary for the dichalcogenolates ligands, facilitating formation of novel chalcogen-centered copper clusters. This report presents three chalcogenide-centered clusters, namely [Cu11S{S2CNnBu2}6(I)3] (1), [Cu11Se{Se2CNnPr2}6(I)3]...