Incorporation of [18O]water in the formation of p-hydroxybenzyl alcohol by the p-cresol methylhydroxylase from Pseudomonas putida
Chemistry
Cresols
0303 health sciences
03 medical and health sciences
Chemical Phenomena
Pseudomonas
Benzyl Compounds
Water
Benzyl Alcohols
Mixed Function Oxygenases
3. Good health
DOI:
10.1042/bj1750345
Publication Date:
2015-08-10T20:13:23Z
AUTHORS (1)
ABSTRACT
In the hydroxylation of the methyl group of p-cresol by an enzyme from Pseudomonas putida the oxygen atom is derived from water. Although a second reaction by the same enzyme converts the product, p-hydroxybenzyl alcohol, into the aldehyde, the alcohol is an enzyme-free intermediate.
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