Multitime correlation functions for single molecule kinetics with fluctuating bottlenecks

• DOI: 10.1063/1.1446433
• Publication Date: 2002-07-26T13:26:45Z
• Authors: Valeri Barsegov; Vladimir Chernyak; Shaul Mukamel
• Keywords: Smoluchowski coagulation equation

Stochastic trajectories in single molecule kinetics coupled to several Gaussian Markovian coordinates are analyzed using a generating function obtained by solving the multidimensional Smoluchowski equation. Multitime correlation functions computed and used identify direct signatures of non-Poissonian resulting from coupling slow coordinates. Effects various degrees between collective with multiple time scales studied.