Accurate quantum mechanical reaction probabilities for the reaction O+H2→OH+H

• DOI: 10.1063/1.453205
• Publication Date: 2002-07-26T13:10:01Z
• Authors: Kenneth Haug; David W. Schwenke; Donald G. Truhlar; Yici Zhang; John Z. H. Zhang; Donald J. Kouri
• Keywords: Momentum (technical analysis); Zero (linguistics)

We report converged quantum mechanical reaction probabilities for O+H2(v=0,1)→OH+H zero total angular momentum as obtained by an ℒ2 expansion of the reactive amplitude density. These provide a benchmark testing approximate dynamical theories, and this is illustrated comparisons to centrifugal sudden distorted wave least-action calculations vibrationally adiabatic threshold energies.