Three-dimensional ionic conduction in the strained electrolytes of solid oxide fuel cells

• DOI: 10.1063/1.4948694
• Publication Date: 2016-05-05T17:00:16Z
• Authors: Yupei Han; Minda Zou; Weiqiang Lv; Yiwu Mao; Wei Wang; Weidong He
• Keywords: 01 natural sciences; 7. Clean energy; 0104 chemical sciences; 3. Good health

Flexible power sources including fuel cells and batteries are the key to realizing flexible electronic devices with pronounced foldability. To understand the bending effects in these devices, theoretical analysis on three-dimensional (3-D) lattice bending is necessary. In this report, we derive a 3-D analytical model to analyze the effects of electrolyte crystal bending on ionic conductivity in flexible solid-state batteries/fuel cells. By employing solid oxide fuel cells as a materials' platform, the intrinsic parameters of bent electrolyte materials, including lattice constant, Young's modulus, and Poisson ratio, are evaluated. Our work facilitates the rational design of highly efficient flexible electrolytes for high-performance flexible device applications.