Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites

• DOI: 10.1073/pnas.0909718106
• Publication Date: 2009-12-01T03:19:59Z
• Authors: David Britt; Hiroyasu Furukawa; Bo Wang; T. Grant Glover; Omar M. Yaghi
• Keywords: Magnesium; Adsorption; Carbon Dioxide; Organic Chemicals; Crystallography, X-Ray; Methane; 01 natural sciences; 7. Clean energy; 0104 chemical sciences

Selective capture of CO 2 , which is essential for natural gas purification and CO 2 sequestration, has been reported in zeolites, porous membranes, and amine solutions. However, all such systems require substantial energy input for release of captured CO 2 , leading to low energy efficiency and high cost. A new class of materials named metal-organic frameworks (MOFs) has also been demonstrated to take up voluminous amounts of CO 2 . However, these studies have been largely limited to equilibrium uptake measurements, which are a poor predictor of separation ability, rather than the more industrially relevant kinetic (dynamic) capacity. Here, we report that a known MOF, Mg-MOF-74, with open magnesium sites, rivals competitive materials in CO 2 capture, with 8.9 wt. % dynamic capacity, and undergoes facile CO 2 release at significantly lower temperature, 80 °C. Mg-MOF-74 offers an excellent balance between dynamic capacity and regeneration. These results demonstrate the potential of MOFs with open metal sites as efficient CO 2 capture media.