Experimental Investigation of PEM Water Electrolyser Stack Performance Under Dynamic Operation Conditions

• DOI: 10.1149/1945-7111/ad4d1f
• Publication Date: 2024-05-17T22:27:47Z
• Authors: Jingjing Liu; Liuyi Huang; Jérôme Leveneur; Holger Fiedler; Sam Clarke; Thea Larsen; John Kennedy; Mark Taylor
• Keywords: 0306 Physical Chemistry (incl. Structural); 3406 Physical chemistry; 4016 Materials engineering; 0303 Macromolecular and Materials Chemistry; 02 engineering and technology; 0912 Materials Engineering; 0210 nano-technology

Water electrolysis has been used to produce green hydrogen, for which identifying optimum operation parameters is crucial to improve its energy efficiency and energy consumption. This paper used a commercial proton exchange membrane (PEM) water electrolyser stack (180 W) to demonstrate the correlation between operating current change, temperature, and water flow rate and their impact on the thermal and electrical performance of the stack. It was found that the current control regime and temperature control can offset the voltage ageing in a long-term operating electrolyser with no negative impact on the H2 production rate. For a controlled decreasing current path, in the medium range of operating current, the stack’s energy efficiency was improved by 5%, and 3.7% specific energy consumption can be saved comparing to the standard operation (57.8 kWh·kg−1H2). The results provide insights into the potential optimisation in operation conditions to further increase cell energy efficiency and reduce energy consumption. This new finding sheds light on developing an energy- and cost-saving operating method for long-term green hydrogen production via water electrolysis.