Experimental Investigation of Reactive Extraction of Levulinic Acid from Aqueous Solutions

• DOI: 10.15255/cabeq.2021.2031
• Publication Date: 2022-01-18T05:24:05Z
• Authors: Anuj Kumar; Diwakar Z. Shende; Kailas Wasewar
• Keywords: reactive extraction; Chemical engineering; number of theoretical stages; diffusivity; TP155-156; levulinic acid; 02 engineering and technology; aqueous solution; 0210 nano-technology; 01 natural sciences; 6. Clean water; 0104 chemical sciences

The separation of levulinic acid from aqueous solutions is costly and non-ecofriendly in many cases. The major concerns are the low concentration of levulinic acid in fermentation broths and industrial downstreams. In this study, reactive extraction of levulinic acid from aqueous phase is proposed and its efficacy was investigated. Various extractants viz. tri-n-butyl phosphate, trioctylamine, and trioctylmethylammonium chloride along with i-octanol as a diluent were used. The extent of separation was investigated and various performance parameters like extraction efficiency, distribution coefficient, equilibrium complexation constant, and loading ratio were estimated. The number of transfer units, diffusivity, and mass transfer considerations were also discussed in the reactive separation system. Finally, the conceptual method was provided for the separation of levulinic acid using efficient reactive separation.