A Magnetic Nanoparticle-Doped Photopolymer for Holographic Recording

• DOI: 10.3390/polym14091858
• Publication Date: 2022-05-02T11:08:58Z
• Authors: Muhammad Irfan; Suzanne Martin; Muhannad Ahmed Ob...; Scott Miller; Frank Kuster; Dermot Brabazon; Izabela Naydenova
• Keywords: volume transmission holographic gratings; Denisyuk reflection hologram; 02 engineering and technology; magnetic nanoparticle-doped holographic gratings; 530; Article; Engineering; photopolymer magnetic nanocomposite; holographic sensor/actuator; functionalised holograms; 0210 nano-technology; photopolymer magnetic nanocomposite; volume transmission holographic gratings; magnetic nanoparticle-doped holographic gratings; holographic sensor/actuator; functionalised holograms; Denisyuk reflection hologram; Optometry

Functionalised holograms are important for applications utilising smart diffractive optical elements for light redirection, shaping and in the development of sensors/indicators. This paper reports on holographic recording in novel magnetic nanocomposites and the observed temperature change in dry layers and liquid samples exposed to alternating magnetic field (AMF). The nanocomposite consists of N-isopropylacrylamide (NIPA)-based polymer doped with magnetic nanoparticles (MNPs), and local heating is achieved through magnetic induction. Here, volume transmission holographic gratings (VTHGs) are recorded with up to 24% diffraction efficiency (DE) in the dry layers of magnetic nanocomposites. The dry layers and liquid samples are then exposed to AMF. Efficient heating was observed in the liquid samples doped with Fe3O4 MNPs of 20 nm average size where the temperature increased from 27 °C to 64 °C after 300 s exposure to 111 mT AMF. The temperature increase in the dry layers doped with the same nanoparticles after exposure to 4.4 mT AMF was observed to be 6 °C. No temperature change was observed in the undoped layers. Additionally, we have successfully recorded Denisyuk holograms in the magnetic nanocomposite materials. The results reveal that the magnetic nanocomposite layers are suitable for recording holograms and need further optimisation in developing holographic indicators for mapping AMFs.