Palladium Catalyzed Double Substitution Reactions of Iodophenol and Iodoaniline Derivatives with Homo-conjugated Com- pounds to Form Cyclic Ether and Cyclic Amines through Homo-conjugated Interaction

• DOI: 10.3987/com-02-9564
• Publication Date: 2009-03-09T04:00:38Z
• Authors: Katsuhiro Saito; Katsuhiko Ono; Makiko Sano; Shingo Kiso; Toshihumi Takeda
• Keywords: 01 natural sciences; 0104 chemical sciences

Palladium(II) acetate catalyzed double substitution reaction of a bicyclo[2.2.2]octadiene derivative (1) with o-substituted iodobenzenes afforded six membered cyclic compounds (3b and 3c) via homo-conjugation type interaction accompanied by five-membered