Lumping Kinetics of Hydrodesulfurization for Crude Longkou Shale Oil

• DOI: 10.4028/www.scientific.net/amr.798-799.12
• Publication Date: 2013-09-11T14:45:24Z
• Authors: Xun Tang; Shu Yuan Li; Chang Tao Yue; Ji Lai He; Yue E Gong
• Keywords: Space velocity

New lumping kinetic models, considering the effects of nitrogen content in product and correction coefficient LHSV, were proposed to describe hydrodesulfurization crude Longkou shale oil. The parameters obtained using nonlinear regression experimental data which conducted a bench-scale trick-bed reactor with NiW/Al 2 O 3 catalyst at various conditions. results show that 4-lump model is optimal model. values apparent activation energies lumps 1, 2, 4 are 51.14, 62.64, 130 166.42kJ/mol, respectively. validation application also investigated.