Conformational Characteristics of p-tert-Butylcalix[6]arene Mono-Alkyl Ester Derivatives

Calixarene Conformational change
DOI: 10.6564/jkmrs.2010.14.2.144 Publication Date: 2011-05-11T21:24:17Z
ABSTRACT
Conformational properties of several mono-alkyl ester derivatives p-tert-butylcalix[6]arene depending on temperatures have been investigated by solution NMR spectroscopy. It is found out that all can adopt a cone-like conformation around room temperature, while the conformational characteristics at high seem to be quite different each other.
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