A5088903506- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Zeolite Catalysis and Synthesis
- Carbon Dioxide Capture Technologies
- Enhanced Oil Recovery Techniques
- Membrane Separation and Gas Transport
- Garlic and Onion Studies
- Magnetism in coordination complexes
- Chemical Looping and Thermochemical Processes
- Pineapple and bromelain studies
- Machine Learning and ELM
- Lanthanide and Transition Metal Complexes
- X-ray Diffraction in Crystallography
- Catalysis and Oxidation Reactions
Polytechnic Institute of Bragança
2012-2018
Universidade do Porto
2012-2017
Instituto Politécnico Nacional
2010
The separation ability of branched alkane isomers ( n HEX, 3MP, 22DMB) the flexible and functionalized microporous iron(III) dicarboxylate MIL‐53(Fe)‐(CF 3 ) 2 solid is evaluated through a combination breakthrough experiments (binary or ternary mixtures), adsorption isotherms, X‐ray diffraction temperature analysis, quasi‐elastic neutron scattering measurements molecular dynamics simulations. A kinetically controlled sieve between di‐branched isomer hexane 22DMB from mixture paraffins...
The sorption equilibrium of methane (CH4) and nitrogen (N2) in binderless beads 5A zeolite is presented between 305 373 K pressures up to 3 bar a static electronic microbalance. adsorbed amount CH4 N2 around 1.6 1.02 mol/kgads, respectively, at bar. A comparison these values with the ones literature shows that adsorption capacity 20% higher than binder commercial materials. isotherms were fitted simplest Langmuir model prediction maximum for both compounds 5.0 mol/kg. heats are −16.6 −15.1...
Screening separation studies with equimolar quaternary mixtures of hexane isomers, namely, n-hexane/3-methylpentane/2,3-dimethylbutane/2,2-dimethylbutane ( n-HEX/3MP/23DMB/22DMB), in the temperature range 343–423 K and partial pressures up to 10 kPa have been performed using three rigid porous metal (III/IV) carboxylate-based metal–organic frameworks (MOFs) different composition topology. These MOFs are denoted as MIL-100(Cr), MIL-125(Ti)-NH 2 MIL-127(Fe). Adsorption study results revealed...