A5012023474- Metal-Organic Frameworks: Synthesis and Applications
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Polyoxometalates: Synthesis and Applications
- Magnetism in coordination complexes
- Advanced Photocatalysis Techniques
- Crystal structures of chemical compounds
- Metal complexes synthesis and properties
- Advanced Nanomaterials in Catalysis
- Lanthanide and Transition Metal Complexes
- Covalent Organic Framework Applications
- Chemical Synthesis and Reactions
- Molecular Sensors and Ion Detection
- Nanocluster Synthesis and Applications
- TiO2 Photocatalysis and Solar Cells
- Advanced biosensing and bioanalysis techniques
- Crystallography and molecular interactions
- Catalysis and Hydrodesulfurization Studies
- Organic and Molecular Conductors Research
- Copper-based nanomaterials and applications
- Vanadium and Halogenation Chemistry
- Water Quality Monitoring and Analysis
- Monoclonal and Polyclonal Antibodies Research
- Analytical Chemistry and Sensors
- Electrochemical sensors and biosensors
Henan University
2015-2024
Harbin Institute of Technology
2021-2024
Nanjing University of Posts and Telecommunications
2021-2023
Kunming Metallurgy College
2023
Guilin University of Electronic Technology
2018-2020
Gansu Academy of Agricultural Sciences
2020
Henan Provincial People's Hospital
2020
Zhengzhou University
1993-2020
Gansu Agricultural University
2020
Kaifeng University
2014-2019
Two unique 22-core sandwich {[Mn6Mo6O37]Ln3[MnMo6O24]} (Ln = La or Pr) units have been assembled, featuring an undisclosed {Mn6Mo6} cluster. This assembly is subsequently integrated into two three-dimensional polyoxometalate organic frameworks, which exhibit one-dimensional hydrophilic hexagonal channels formed by six intertwined 63 helical chains, leading to effective proton conduction primarily facilitated abundance of water molecules within the channels.
A certain amount of Na<sub>2</sub>S<sub>2</sub>O<sub>3</sub>·5H<sub>2</sub>O solution added to the containing cadmium ions form Cd/CdS photocatalysts could remove and produce hydrogen efficiently under visible light irradiation.
A new tungstovanadate K4[VW12O40]·21H2O has been prepared by a simple method first and then isolated as [C2(MIM)2]2VW12O40 (VW12-IL) cation exchange (MIM = 1-methylimidazolium). The designed VW12-IL is employed catalyst in an extraction coupled oxidation desulfurization system, which could reach both 100% sulfur removal efficiency sulfone product selectivity 20 min with high turnover frequency value (TOF: 53.2 h–1). Clean fuel products are achieved simultaneously after the reaction,...
Abstract Wearable human‐machine interaction (HMI) is an advanced technology that realizes operations, collaborations, and interactions between human machines in a co‐located or coordinated way. As the core component of wearable HMI electronics, flexible sensor desirable to be intelligent, accurate, collaborative, multifunctional for feedback control. Here, MXene/polyacrylic acid (PAA) hydrogel prepared by radical polymerization. strain sensor, it exhibits high sensitivity (gauge factor...
Two 2:2 types of monolanthanide substituted polyoxometalates [{(α-PW11O39H)Ln(H2O)3}2]6− (Ln = NdIII for 1 and GdIII 2) [{(α-PW11O39)Ln(H2O)(η2,μ-1,1)-CH3COO}2]10− SmIII 3, EuIII 4, 5, TbIII 6, HoIII 7 ErIII 8) have been synthesized in aqueous solution characterized by elemental analyses, IR spectra, UV−vis−NIR thermogravimatric analyses single-crystal X-ray diffraction. The common structural features are that they constructed from monovacant Keggin-type polyoxoanions [α-PW11O39]7− trivalent...
A two-dimensional porous framework, which was formed from neutral discrete hexanuclear copper clusters via self-assembly, exhibited highly selective absorption of aromatic molecules in water with special fluorescent response.
A polyoxometalate-based lanthanide−organic framework was achieved using the {[Ho4(dpdo)8(H2O)16BW12O40] (H2O)2}7+ nanocage as a secondary building block for heterogeneous catalysis of phosphodiester cleavage in an aqueous solution.
The incorporation of oxygen vacancy defects into the catalysts has been attracting significant interest for regulating performance photocatalysts. Single-atomic-site metal have also paid ever-growing attention because they maximized atom efficiency and thus generated excellent catalytic performance. Herein, we report interaction decorated atomically dispersed Pt to boost efficient photocatalytic process. Compared with TiO2 without defects, under same theoretical amount support, all...
With the booming growth of flexible human-computer interactions and telecommunications, it is desirable to fabricate a high-sensitivity strain sensor monitor human movement develop an electromagnetic interference (EMI) shielding materials protect modern microelectronics humans from damage. Herein, biocompatible, stretchable, compressible cellulose/MXene hydrogel has been prepared first realize dual-functional applications in EMI shielding. Two-dimensional MXene nanosheets serve as conductive...
Hydrogen-bonded organic frameworks (HOFs) with inherent well-defined hydrogen-bond networks are promising proton conduction materials. Herein, four three-dimensional HOFs were controllably assembled from 1,2,4,5-benzenetetracarboxylic acid and guanidinium of different chain lengths certain ratios, in which GC-1 has undergone a water-induced single-crystal-to-single-crystal (SCSC) transformation to more stable GC-2 successive π–π stacking interactions. Notably, the ideal single-crystal sample...
Abstract The “visible” proton‐conducting pathway offers a distinct advantage for researching the mechanism of proton conducting materials at molecular level and developing new materials. To achieve this, three crystalline are constructed via acid–base chemistry based on phosphomolybdic acid diversfied guanidine, namely, (CN 3 H 6 ) (PMo 12 O 40 2 ·H (GH–PMo ), 4 7 )·H (AGH–PMo 5 8 )·3.5H (DAGH–PMo ). Proton conductivity GH–PMo in [001] direction reaches up to 0.19 S cm −1 85 °C 98% RH, as...
Achieving long-term stable deep desulfurization at room temperature and recovering high value-added sulfone products is a challenge present. Herein, series of catalysts [Cnmim]5VW12O40Br (CnVW12, 1-alkyl-3-methylimidazolium bromide tungstovanadate, n = 4, 8, 16) were presented for the catalytic oxidation dibenzothiophene (DBT) its derivatives. Factors affecting reaction process, such as amount catalyst, oxidant, temperature, systematically discussed. C16VW12 showed higher performance, 100%...