A5001555081- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Advanced Nanomaterials in Catalysis
- Lanthanide and Transition Metal Complexes
- Polyoxometalates: Synthesis and Applications
- Metal complexes synthesis and properties
- Carbon dioxide utilization in catalysis
- Metal-Catalyzed Oxygenation Mechanisms
- Advanced Polymer Synthesis and Characterization
- Electron Spin Resonance Studies
- Molecular Junctions and Nanostructures
- Ferrocene Chemistry and Applications
- Crystallography and molecular interactions
- Microwave-Assisted Synthesis and Applications
- biodegradable polymer synthesis and properties
- Catalytic Cross-Coupling Reactions
- Organometallic Complex Synthesis and Catalysis
RWTH Aachen University
2013-2019
Mixed-valence polyoxovanadates(IV/V) have emerged as one of the most intricate class supramolecular all-inorganic host species, able to encapsulate a wide variety smaller guest templates during their self-assembly formation process. As showcased herein, incorporation guests, though governed solely by ultra-weak electrostatic and van der Waals interactions, can cause drastic effects on electronic magnetic characteristics shell complex polyoxovanadate. We address question methodology for...
One-dimensional chain coordination polymers based on hexanuclear iron(III) pivalate building blocks and 1,4-dioxane (diox) or 4,4'-bipyridine (4,4'-bpy) bridging ligands, [Fe6O2(O2CH2)(O2CCMe3)12(diox)]n (1) [Fe6O2(O2CH2)(O2CCMe3)12(4,4'-bpy)]n (2), showcase the utility of angular overlap model, implemented in program wxJFinder, predictive identification relative role intra- intercluster coupling.
Bistable spin crossover complexes such as [Fe{HB(pz)3}2] (pzH = pyrazole) show promise for sensor applications and electrically-controlled data storage units, but exploiting their potential hinges on integration into a functional environment. We here present system enabling covalent post-functionalization steps in both symmetric asymmetric patterns, based the amine-functionalized complex [Fe{HB(4-NH2pz)(pz)2}2], obtained by reduction of nitro analogue. The building block aspects...
Abstract Crystals of (Et 4 N) 6 [(VO 2 F )HV 22 O 54 ] are prepared by mixing Et NBF and (H 8 [H 9 V 19 50 ]·11H in the molar ratio 8.7:0.39 aqueous solution (80 °C, 72 h, 79% yield).
Abstract Invited for the cover of this issue is group Paul Kögerler from RWTH Aachen University, Germany. The image shows an aluminum sheet painted with thermochromic lacquer based on functionalized derivatives iron(II) bis(tris(pyrazolyl)borate) complexes.