Marcin E. Witkowski

ORCID: 0000-0001-6282-8610
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Research Areas
  • Luminescence Properties of Advanced Materials
  • Radiation Detection and Scintillator Technologies
  • Perovskite Materials and Applications
  • Atomic and Subatomic Physics Research
  • Solid-state spectroscopy and crystallography
  • Ga2O3 and related materials
  • Polish socio-economic development
  • Limits and Structures in Graph Theory
  • Terahertz technology and applications
  • Advanced Semiconductor Detectors and Materials
  • Crystallization and Solubility Studies
  • Nuclear materials and radiation effects
  • Nuclear Physics and Applications
  • Advanced Photocatalysis Techniques
  • X-ray Diffraction in Crystallography
  • Optical properties and cooling technologies in crystalline materials
  • Crystal Structures and Properties
  • Medical Imaging Techniques and Applications
  • Inorganic Fluorides and Related Compounds
  • Glass properties and applications
  • ZnO doping and properties
  • graph theory and CDMA systems
  • Optical and Acousto-Optic Technologies
  • Integrated Water Resources Management
  • Digital Radiography and Breast Imaging

Institute of Physics
2014-2025

Nicolaus Copernicus University
2014-2025

Abstract Two-dimensional lead halide perovskites have demonstrated their potential as high-performance scintillators for X- and gamma-ray detection, while also being low-cost. Here we adopt lithium chemical doping in two-dimensional phenethylammonium bromide (PEA) 2 PbBr 4 perovskite crystals to improve the properties add functionalities with other radiation detections. Li is confirmed by X-ray photoemission spectroscopy scintillation mechanisms are explored via temperature dependent...

10.1038/s43246-020-0038-x article EN cc-by Communications Materials 2020-06-24

Two-dimensional (2D) hybrid lead halide perovskites are potential candidates for high light yield scintillators as they have small band gaps between 3 and 4 eV large exciton-binding energy. Here, we discuss the scintillation properties from a total of 11 organic/inorganic perovskite crystals with two already reported crystals, (PEA)2PbBr4 (EDBE)PbBr4. Their photoluminescence X-ray luminescence (XL) spectra dominated by narrow broad emissions, correspond to free exciton self-trapped exciton,...

10.1021/acs.chemmater.0c02789 article EN Chemistry of Materials 2020-09-15

Commensurate Lithium doping of two-dimensional lead halide perovskites leads to improved scintillation properties, with enhanced light yield, narrower energy resolution, higher radiation hardness and faster decay.

10.1039/d0tc05647b article EN Journal of Materials Chemistry C 2021-01-01

Two-dimensional hybrid-organic-inorganic perovskite (2D-HOIP) lead bromide crystals have demonstrated great potential as scintillators with high light yields and fast decay times while also being low cost solution-processable materials for wide energy radiation detection. Ion doping has been shown to be a very promising avenue improvements of the scintillation properties 2D-HOIP crystals. In this paper, we discuss effect rubidium (Rb) on two previously reported single crystals, BA2PbBr4...

10.1021/acs.inorgchem.3c00270 article EN cc-by Inorganic Chemistry 2023-05-26

Demonstration of how rational design affects self-trapped emission characteristics and scintillation properties in mechanochemically synthesised caesium copper halide perovskites.

10.1039/d3tc03977c article EN Journal of Materials Chemistry C 2024-01-01

Temperature- and dose-dependent measurements of X-ray luminescence (XL) in various perovskite single crystals are reported. For methylammonium lead halide perovskites (MAPbX3, MA = methylammonium, X Cl, Br, or I), the quenching temperature XL intensities shifts to lower temperatures sequence from Cl I. This is strongly affected by decrease thermal activation energy ΔEq 53 ± 3 6 1 meV. We replace MAPbBr3 with Cs observe that even temperature. But unlike MAPbX3 perovskites, CsPbBr3 now...

10.1021/acs.jpcc.8b03622 article EN The Journal of Physical Chemistry C 2018-06-26

Among the two-dimensional hybrid organic-inorganic perovskites, PEA2PbBr4 is one of best scintillators combining high light yield and fast nanosecond decay time. However, it has limited sensitivity to X-ray positron emission tomography because insufficient mass density effective atomic number. In this article, we show that exchanging halide from bromide iodide allows shorten absorption length as much two times for energies. We present a detailed study on scintillation properties self-grown...

10.1016/j.mtchem.2023.101455 article EN cc-by Materials Today Chemistry 2023-03-13

Quantum-well (QW) hybrid organic-inorganic perovskite (HOIP) crystals, e.g., A2PbX4 (A = BA, PEA; X Br, I), demonstrated significant potentials as scintillating materials for wide energy radiation detection compared to their individual three-dimensional (3D) counterparts, BPbX3 (B MA). Inserting 3D into QW structures resulted in new structures, namely A2BPb2X7 and they may have promising optical scintillation properties toward higher mass density fast timing scintillators. In this article,...

10.1021/acs.jpcc.3c00824 article EN cc-by The Journal of Physical Chemistry C 2023-04-26

Two-dimensional (2D) hybrid organic-inorganic perovskite (HOIP) crystals show promise as scintillating materials for wide-energy radiation detection, outperforming their three-dimensional counterparts. In this study, we synthesized single of (PEA

10.1021/acsami.4c01741 article EN cc-by ACS Applied Materials & Interfaces 2024-05-03

Lead halide perovskite (LHP) nanocrystals (NCs) have recently attracted attention due to both their high quantum yield and potential for X-ray imaging applications. In this paper, we investigated the scintillation properties of three different LHP NCs; CsPbBr3, FAPbBr3, CsPbI3. The featured NCs exhibited excited luminescence (XL) at cryogenic temperatures. While FAPbBr3 CsPbI3 display thermal quenching, CsPbBr3 show negative quenching XL temperatures, with a light 24,000 ± 2,100 photons/MeV...

10.1021/acs.jpcc.1c03392 article EN The Journal of Physical Chemistry C 2021-06-18

Understanding the scintillation properties of Cu- and Sn-based two-dimensional perovskite crystals while comparing them to those high-light-yield fast Pb-based crystals.

10.1039/d2ma00258b article EN cc-by Materials Advances 2022-01-01

Scintillators fabricated from organic–inorganic layered perovskites have attracted wide attention due to their excellent properties, including fast decay times, superior light yield, and high exciton binding energy. In relation optoelectronic hybrid are known for tunability, which could be manipulated by modifying the organic cations. this study, we investigate optical scintillation properties of lead halide A2PbBr4, where A vary amylammonium (AA), hexylammonium (HA), octylammonium (OA),...

10.1021/acsaem.3c00340 article EN ACS Applied Energy Materials 2023-05-17

Low-dimensional bismuth-based hybrid organic-inorganic halide perovskites (Bi-HOIPs) are intriguing scintillating materials due to their anisotropic nature. However, a systematic investigation of Bi-HOIPs framework for X-ray detection imaging remains lacking. In...

10.1039/d4tc04390a article EN Journal of Materials Chemistry C 2025-01-01

CsPbBr3 quantum dots (QDs) have recently gained much interest due to their excellent optical and scintillation properties potential for X-ray imaging applications. In this study, we blended QDs with resin at different QD concentrations achieve thick films protect the from environmental moisture. Then, are investigated compared traditional commercial scintillators, CsI:Tl microcolumns, Gadox layers. The QD-resin sheets show a high light yield of up 21 500 photons/MeV room temperature...

10.1021/acsami.1c16171 article EN ACS Applied Materials & Interfaces 2021-12-02

Two-dimensional (2-D) Ruddlesden-Popper (RP) hybrid organic-inorganic perovskite (HOIP) crystals, A <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> XY xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> [A = Phenethylammonium (PEA), Butylammonium (BA); X Pb, Sn, Cu, Mn; Y Cl, Br, I] have been a subject of interest for solution-processable scintillators the past two decades, due to possibility grow high-quality and large crystals with...

10.1109/tns.2023.3267636 article EN IEEE Transactions on Nuclear Science 2023-04-17
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