A5071920812- Advanced Photocatalysis Techniques
- Electrocatalysts for Energy Conversion
- Advanced battery technologies research
- Gas Sensing Nanomaterials and Sensors
- Metal-Organic Frameworks: Synthesis and Applications
- Copper-based nanomaterials and applications
- Catalytic Processes in Materials Science
- Electrochemical Analysis and Applications
- Covalent Organic Framework Applications
- Fuel Cells and Related Materials
- Supercapacitor Materials and Fabrication
- Nanomaterials for catalytic reactions
- Scheduling and Optimization Algorithms
- CO2 Reduction Techniques and Catalysts
- Carbon dioxide utilization in catalysis
- Perovskite Materials and Applications
- Supply Chain and Inventory Management
- Sustainable Supply Chain Management
- Innovation and Knowledge Management
- Job Satisfaction and Organizational Behavior
- Eicosanoids and Hypertension Pharmacology
- Qualitative Comparative Analysis Research
- Technology Use by Older Adults
- Ferroptosis and cancer prognosis
- Hip and Femur Fractures
Qingdao University
2019-2025
Qingdao Municipal Hospital
2025
Shanghai Tenth People's Hospital
2022-2024
Technical University of Munich
2024
Ocean University of China
2021-2024
Taian City Central Hospital
2024
Tongji University
2008-2024
Guangzhou Education Bureau
2024
University of Chinese Academy of Sciences
2023
Qingdao Institute of Bioenergy and Bioprocess Technology
2023
The oxygen evolution reaction (OER) in water splitting plays a critical role some clean energy production systems. Transition-metal oxides as one of the most common OER electrocatalysts have been widely explored; however, their activity is limited by low electrical conductivity, slow mass transfer, and inadequate active sites. Herein, we develop feasible strategy which layered two-dimensional metal–organic frameworks (2D MOFs) act templates to construct metal oxide/carbon (MOx/C, M = Co, Ni,...
Employing seawater splitting systems to generate hydrogen can be economically advantageous but still remains challenging, particularly for designing efficient and high Cl- -corrosion resistant trifunctional catalysts toward the oxygen reduction reaction (ORR), evolution (OER), (HER). Herein, single CoNC with well-defined symmetric CoN4 sites are selected as atomic platforms electronic structure tailoring. Density function theory reveals that P-doping into lead formation of asymmetric...
Abstract Despite numerous inherent merits of metal–organic frameworks (MOFs), structural fragility has imposed great restrictions on their wider involvement in many applications, such as catalysis. Herein, a strategy for enhancing stability and enabling functionality labile Zr(IV)‐MOF been proposed by situ porphyrin substitution. A size‐ geometry‐matched robust linear ligand 4,4′‐(porphyrin‐5,15‐diyl)dibenzolate (DCPP 2− ) is selected to replace the 4,4′‐(1,3,6,8‐tetraoxobenzo[ lmn...
The exploration of efficient electrocatalysts is the central issue for boosting overall efficiency water splitting. Herein, pertinently creating active sites and improving conductivity metal-organic frameworks (MOFs) proposed to tailor electrocatalytic properties An Ni(II)-MOF nanosheet array presented as an ideal material model a facile alkali-etched strategy developed break its NiO bonds accompanied with introduction extra-framework K cations, which contribute highly open metal largely...
Constructing stable palladium(II)-based metal–organic frameworks (MOFs) would unlock more opportunities for MOF chemistry, particularly toward applications in catalysis. However, their availability is limited by synthetic challenges due to the inertness of Pd–ligand coordination bond, as well strong tendency Pd(II) source be reduced under typical solvothermal conditions. Under guidance reticular herein, we present first example an azolate Pd-MOF, BUT-33(Pd), obtained via a deuterated...
Hierarchical-pore Pd@Co3O4, Pd@Co3O4/C, and Pd@Co/CNT (CNT = carbon nanotube) were fabricated via the one-step pyrolysis of palladium@zeolitic-imidazolate-framework-67 (Pd@ZIF-67); these catalysts employed as heterogeneous displayed excellent performance in Heck reaction. These Pd@ZIF-67 derivatives retain skeleton precursor provide abundant exposed Pd active sites, treatment creates rich hierarchical pores affording a convenient path for reaction substrates accessing sites. As result, they...
The structural symmetry breaking of a highly crystalline substance towards non-crystal phase construction, particularly involving self-healing process after grain destruction, is beset by difficulties and critical for water splitting.
Abstract Amorphous metal‐organic frameworks (MOFs) with aperiodic atomic arrangements, featuring high intrinsic activity and rich active sites, have emerged as promising oxygen evolution reaction (OER) catalysts. However, the quantitative structure‐activity relationships (SARs) that determine OER activity, key to a rational catalyst design, remain unresolved. Inspired by controllable amorphization engineering, amorphous MOF structures are rationally constructed an ideal platform explore SAR...
Abstract Transition metal‐nitrogen‐carbon‐based catalysts (M‐N‐C) serve as promising alternatives for oxygen reduction reaction (ORR). However, their synthesis generally involves complex pyrolysis reactions, resulting in high structure heterogeneity and consequently making it difficult to distinguish the catalytic active sites. Herein, atomically dispersed Fe 2 on hollow carbon spheres are synthesized model insight into sites at atomic level. By virtue of systematic SCN − poisoning...
Pd-based catalysts have been widely applied in hydrogenation reactions for production of both bulk and fine chemicals; however, selective efficient substrates with multiple functional groups is challenging. Here, we synthesize the C-doped Pd NPs confined hollow-structured carbons a closed shell (C-Pd@HCS), single hole (C-Pd@HCH), bowl-like (C-Pd@HCB). Based on three comparative samples, void-confinement effects phenol are investigated. It found that reaction rate always decelerated gradually...
Abstracts Overexpression of methyltransferase-like 3 (METTL3) is significantly correlated with the malignancy lung cancer (LC). In present study, we demonstrated that METTL3 had higher levels in LC tissues relative to normal tissues. showed superior sensitivity and specificity for diagnosis identification functions. addition, silencing resulted enhanced ferroptosis sensitivity, whereas overexpression exhibited opposite effect. Inhibition impeded growth cell-derived xenografts. Further...
ABSTRACT Hydrogen sulfide (H 2 S), as a toxic gas, is one of the occupational hazards to workers' health. Traditional H S sensors often suffer from external circuits, measurement systems, liquid‐phase reactions, or high detection limits. Herein, colorimetric sensor for was developed by incorporating dye [lead acetate, Pb(OAc) ] into polyacrylamide (PAM)/polyvinyl alcohol (PVA) hydrogel. Benefitting interpenetrating polymer network, non‐covalent interactions such hydrogen bonds and dense...
The development of sustainable catalysts to simultaneously improve activity and selectivity remains a challenge. Herein, it is demonstrated that metal nanoparticles (MNPs) can be encapsulated into yolk-shell metal-organic framework (MOF) with controllable spatial localization optimize catalytic performance. When the MNPs are located in void space between shell core MOF, resulting MNPs@MOF composites show both high toward hydrogenation α,β-unsaturated aldehydes. In particular, easily...