A5044526266- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Organic and Molecular Conductors Research
- Gas Sensing Nanomaterials and Sensors
- Electrochemical Analysis and Applications
- Advancements in Battery Materials
- Molecular Sensors and Ion Detection
- Cell Adhesion Molecules Research
- S100 Proteins and Annexins
- Catalytic Processes in Materials Science
- RNA and protein synthesis mechanisms
- Advanced battery technologies research
- Nanomaterials for catalytic reactions
- Advanced biosensing and bioanalysis techniques
- Advanced Photocatalysis Techniques
- Analytical Chemistry and Sensors
- Corrosion Behavior and Inhibition
- Advanced Nanomaterials in Catalysis
- Advanced Chemical Sensor Technologies
- HER2/EGFR in Cancer Research
University of Oregon
2022-2024
Zero to Three
2024
Metal-linker bonds serve as the “glue” that binds metal ions to multitopic organic ligands in porous materials known metal–organic frameworks (MOFs).
Redox intercalation involves coupled ion-electron motion within host materials, finding extensive application in energy storage, electrocatalysis, sensing, and optoelectronics. Monodisperse MOF nanocrystals, compared to their bulk phases, exhibit accelerated mass transport kinetics that promote redox inside nanoconfined pores. However, nanosizing MOFs significantly increases external surface-to-volume ratios, making the chemistry into nanocrystals difficult understand due challenge of...
Anion sensing technology is motivated by the widespread and critical roles played anions in biological systems environment. Electrochemical approaches comprise a major portion of this field but so far have relied on redox-active molecules appended to electrodes that often lack ability produce mixtures distinct signatures from different anions. Here, nanocrystalline films conductive metal–organic framework (MOF) Cr(1,2,3-triazolate)2 are used differentiate based size, which consequently...
Size reduction offers a synthetic route to tunable phase change behavior. Preparing materials as nanoparticles causes drastic modulations critical temperatures (
Computing atomic and molecular volumes from DFT ab initio -based electric fields.
Although metal–organic framework (MOF) photocatalysts have become ubiquitous, basic aspects of their photoredox mechanisms remain elusive.
Size reduction offers a synthetic route to tunable phase change behavior. Preparing materials as nanoparticles causes drastic modulations critical temperatures (Tc), hysteresis widths, and the “sharpness” of first-order versus second-order transitions. A microscopic picture chemistry underlying this size dependence in phenomena ranging from melting superconductivity remains debated. As case study with broad implica-tions, we report that size-dependent spin crossover (SCO) nanocrystals...
Nanoparticles of metal-organic frameworks (nanoMOFs) possess the unusual combination both internal and external surfaces. While surfaces have been focus fundamental applications-based MOF studies, chemistry remains scarcely understood. Herein we report that specific ion interactions with nanoparticles Cu(1,2,3-triazolate)