Corrosion poses a significant challenge in industrial sectors that handle metallic materials. The objective of this study was to evaluate the feasibility employing cost-effective, organic, and eco-friendly solution derived from discarded coffee grounds, known as waste extract (CE), mitigate corrosion rate carbon steel an acidic environment comprising 0.5 M hydrochloric acid (HCL) with varying concentrations ranging 20 100 ppm. This research aims explore prospective utilization inhibitory...

In this work, we report the synthesis of two Schiff bases substituted gallic acid derivatives via amidation reaction and their characterization using 1H-NMR spectroscopy to study inhibition performance on aggressive attack HCl mild steel (MS). The inhibitive was examined chemical (weight loss) electrochemical (Tafel EIS) test methods. results indicate that these significantly suppress dissolution rate adsorption phenomena, which correlates Langmuir model. Tafel data display mixed-type...

Improving oil production for high-salinity reservoirs using polymer flooding is challenging due to chemical and mechanical degradations. This study developed two biodegradable biopolymers based on graft copolymerization of guar gum (GG) with different co-monomers, which are acrylamide (Am) 2-acrylamido-2-methylpropane sulfonic acid (AMPS), cross-linked by N,N′-methylene bisacrylamide (MBA) face these challenges. The newly synthesized gum-based hydrogels, GG-g-poly(Am-AMPS) (GH)...

Uranium is the backbone of nuclear fuel used for energy production but still a hazardous environmental contaminant; thus, its removal and recovery are important security protection. So far, development biocompatible, efficient, economical, reusable adsorbents uranium challenge. In this work, new orange peel biochar-based hydrogel composite was prepared by graft polymerization using guar gum acrylamide. The composite's structural, morphological, thermal characteristics were investigated via...

Abstract The effectiveness of modified guar gum ( Cyamopsis tetragonoloba ) as a Cd(II) and Cu(II) adsorbent in aquatic media was investigated. Synthesis based on copolymerization with 2‐Acrylamido‐2‐methyl‐1‐propane sulfonic acid acrylamide presence methylene bis‐acrylamide cross linker the form hydrogel adsorbent. Various analytical techniques were employed to describe surface morphology Adsorption tests carried out under different conditions dose (10–50 mg), initial concentration (25–150...

Two sets of hydrogel materials based on guar gum were prepared by grafting onto acrylic acid/acrylamide and acid/N-isopropylacrylamide copolymers using persulphate radical as an initiator N,N′ methylenebisacrylamide a cross linker. The hydrogels denoted AA-AcM-GG AA-NIPAM-GG respectively. They characterized FTIR Spectroscopy SEM. effect some composition variables the swelling performance PA-GG was thoroughly studied. Furthermore, behavior monitored function temperature electrolyte...

Recently, scientist study the role of surfactants for carbon steel corrosion protection. In present study, newly tetra-cationic surfactant (CS4: 1,N1'-(ethane-1,2-diyl) bis (N1, N2-didodecyl-N2-(2- (((E)-3-hydroxy-4-methoxy-benzylidene)amino)ethyl)ethane-1,2-diaminium) chloride) based on Schiff-base compound(5,5'-((1E,17E)-2,5,8,11,14,17-hexaazaoctadeca-1,17-diene-1,18-diyl)bis(2-methoxyphenol) was synthesised, purified and characterized using FTIR 1HNMR spectroscopy. The synthesized...

Dodecyl dimethyl benzyl ammonium bromide (DDBAB) was used as a corrosion inhibitor for carbon steel pipelines in 8% sulfamic acid solution during matrix acidizing operations.

Abstract Effects of using a synthesized aminothiazole (BZ) Schiff base at different concentrations with and without the addition 1 mM KI on corrosion mitigation mild steel (MS) in 0.5 M sulphuric acid (H 2 SO 4 ) solutions are studied electrochemically direct alternating currents (DC AC) techniques. Besides, adsorption thermodynamic parameters calculated temperature range 293–323 K. Furthermore, Mott‐Schottky analysis is used to study type oxide layer MS surface. Quantum chemical...

The inhibitory impact of low-cost synthesized pyrazoline derivatives named Pz series (Pz1 and Pz2) on the corrosion API 5L X60 carbon steel in 5 M HCl was inspected to serve as inhibitors against such a solution for its usage oilfield well acidization process. Also, same compounds were unitized biocides sulfate-reducing bacteria (SRBs) inhibit microbial-induced effect. This study conducted via several electrochemical techniques, namely, potentiodynamic polarization (EP) impedance...

The corrosion performance of carbon steel was tested in four polymeric ionic liquids (PILs) that differed only the fatty acid linked to chitosan (CS) amine group. measurements were implemented involved hydrogen evolution rate (HER), gravimetric measurements, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and quantum chemical estimations. morphology elements arranged on metal considered by a scanning electron microscopy (SEM) system attached an energy...

Ionic liquids have significantly enhanced ecofriendly benefits compared to the traditional inhibitors. In present work, new four polymeric ionic based on benzoimidazole derivatives were synthesized through reaction of 2-styryl-1H-benzo[d]imidazole with alkyl halide form PIL1. Then, Cl– anions exchanged different neutralization other investigated polymers. Their structures chemically elucidated using Fourier transform infrared spectroscopy, 1H NMR, and 13C NMR. influence carbon steel (CS) as...

Climate change is being currently faced globally; controlling the plastic waste and gas emission aimed to reduce their hazardous effects. In this work, polyethylene terephthalate (PET) polyvinyl chloride (PVC) polymer wastes are used as fillers calcium silicate. Chemical treatment was performed get best efficiency of binder material with treated PET (TPET) PVC (TPVC). The silicate, new nonhydraulic dicalcium synthesized by sintering. A environmentally friendly concrete, based on different...

The hazards of polymer waste and emitted gas on the environment pose a global challenge. As trial to control this, current work aims reuse mix (PM) as fillers in calcium silicate prepare new composites environmentally friendly concrete. PM was first subjected treatment obtain treated (TPM) then filled dicalcium cement with different concentrations. microstructural characterizations declare successful preparation base material. After curing reaction, precipitated carbonate main product is...

Waste polyethylene (WPE) and virgin (VPE) (50:50) thermoplastic have been melt-mixed with biochar (BC) made from orange peels at ratios of 5, 10, 15(Phr) to evaluate how the filler content affected mechanical, thermal, optical, electrical conductivity, electromagnetic interference (EMI). γ-rays was applied prepared specimens assess radiation created biocomposites. From obtained results, combination BC γ-rays, doses up 100 kGy, resulted in an enhanced mechanical property, particularly for...