A5075865104- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Crystal structures of chemical compounds
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Carbon dioxide utilization in catalysis
- Organoboron and organosilicon chemistry
- Organometallic Complex Synthesis and Catalysis
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Magnetism in coordination complexes
- Synthesis and characterization of novel inorganic/organometallic compounds
- CO2 Reduction Techniques and Catalysts
- Catalytic Cross-Coupling Reactions
- Fuel Cells and Related Materials
- Inorganic Fluorides and Related Compounds
- Fluorine in Organic Chemistry
- Organic Light-Emitting Diodes Research
- Asymmetric Hydrogenation and Catalysis
- Catalytic Processes in Materials Science
- Metal-Organic Frameworks: Synthesis and Applications
- Synthesis and Reactions of Organic Compounds
- Advanced battery technologies research
- Molecular Sensors and Ion Detection
- Coordination Chemistry and Organometallics
- Ionic liquids properties and applications
Columbia University
2019-2024
Yeshiva University
2015
Abstract A luminescent bimetallic Au I complex comprised of N ‐heterocyclic carbene (NHC) and carbazole (Cz) ligands, that is, (NHC’)Au(NHC)AuCz has been synthesized studied. Both ligands in the act as electron acceptors tandem to increase energy separation between ground excited state, which is higher than those found either monometallic analogue, (NHC)AuCz (NHC’)AuCz. coplanar geometry designed into ensures sufficient electronic coupling π‐orbitals impart a strong oscillator strength...
The mesoionic compound (1,4-diphenyl-1,2,4-triazol-4-ium-3-yl)phenylazanide, commonly referred to as Nitron, has been employed a "crypto-NHC" afford 1,2,4-triazolylidene compounds of nickel, palladium, and iridium. Specifically, Nitron reacts with NiBr2, PdCl2, [Ir(COD)Cl]2 the N-heterocyclic carbene complexes (NitronNHC)2NiBr2, (NitronNHC)2PdCl2, (NitronNHC)Ir(COD)Cl, respectively. lattermost (i) CO dicarbonyl (NitronNHC)Ir(CO)2Cl (ii) CO, in presence PPh3, monocarbonyl...
The reactions of bis(2-pyridylthio)methane with Me2Zn and Zn[N(SiMe3)2]2 afford [Bptm]ZnMe [Bptm]ZnN(SiMe3)2, thereby providing access to a variety other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves as catalyst for reduction CO2 carbonyl compounds via hydrosilylation hydroboration.
The zinc hydride compound, [Tptm]ZnH, may achieve the reduction of CO2 by (RO)3SiH (R = Me, Et) to methanol oxidation level, (MeO)xSi(OR)4-x, via formate species, HCO2Si(OR)3. However, because insertion into Zn-H bond is more facile than HCO2Si(OR)3, conversion HCO2Si(OR)3 level only occurs a significant extent in absence CO2.
The zerovalent carbodiphosphorane, (Ph<sub>3</sub>P)<sub>2</sub>C, reacts with Me<sub>3</sub>Al and Me<sub>3</sub>Ga to afford the adducts, [(Ph<sub>3</sub>P)<sub>2</sub>C]MMe<sub>3</sub>(M = Al, Ga), whereas Me<sub>2</sub>Zn Me<sub>2</sub>Mg react mononuclear dinuclear cyclometalated derivatives.
The silatrane hydride compound, [N(CH 2 CH O) 3 ]SiH, reacts with CO in the presence of [tris(2-pyridylthio)methyl]zinc complex, [Tptm]ZnH, to afford silyl formate and methoxide derivatives, ]SiO ]SiOCH . molecular structure has been determined by X-ray diffraction, thereby demonstrating that ligand adopts a distal conformation which uncoordinated oxygen atom resides trans-like disposition relative silicon. Density functional theory calculations indicate atrane motif is flexible, such energy...
The previously reported novel cadmium carbonyl compound, [Cd(CO)<sub>3</sub>(C<sub>6</sub>H<sub>3</sub>Cl)]<sub>4</sub>, is better formulated as the rhenium [Re(CO)<sub>3</sub>(C<sub>4</sub>N<sub>2</sub>H<sub>3</sub>S)]<sub>4</sub>.
Nickel cyano carbonyl catalyzed carbon monoxide oxidation in basic solution under ambient conditions.
The bis(2-pyridylthio)methyl ligand, [Bptm], has been employed in the synthesis of {[Bptm]Zn(μ-F)}2, a rare example an organozinc fluoride compound. dimeric nature which possesses uncommon [Zn(μ-F)]2 motif, contrasts with monomeric structures reported for other halide derivatives, [Bptm]ZnX (X = Cl, Br, I); this difference is supported by density functional theory calculations indicate that derivative favors form bridging ligands, whereas derivatives favor terminal ligands. {[Bptm]Zn(μ-F)}2...
Metal complexes of 3,5-diisopropylsalicylate are reported to have anti-inflammatory and anti-convulsant activities. The title binuclear copper complex, [Cu 2 (C 13 H 17 O 3 ) 4 6 OS) ] or [Cu(II) (3,5-DIPS) (DMSO) ], contains two five-coordinate atoms that bridged by four ligands capped axial dimethyl sulfoxide moieties. Each atom is attached oxygen in an almost square-planar fashion, with the addition a DMSO ligand apical position leading square-pyramidal arrangement. hydroxy group...
Coordination compounds of polydentate nitrogen ligands with metals are used extensively in research areas such as catalysis, and models complex active sites enzymes bioinorganic chemistry. Tris(2-pyridylmethyl)amine (TPA) is a tripodal tetradentate ligand that known to form coordination metals, including copper, iron zinc. The related compound, tris[(6-bromopyridin-2-yl)methyl]amine (TPABr 3 ), C 18 H 15 Br N 4 , which possesses bromine atom on the 6-position each three pyridyl moieties,...
The title tetra-nuclear copper complex, [Cu