Because of the toxicity inorganic arsenic (iAs), only iAs needs to be monitored in food and feedstuff. This demands development easy quick analytical methods screen large number samples. work focuses on hydride generation (HG) coupled with an ICPMS as detector where HG is added a selective step determine gaseous phase while organically bound As remains solution. forms volatile arsine species high efficiency when treated NaBH4 at acidic conditions, whereas most other organoarsenic compounds...

Herein, we describe the highly efficient photochemical vapor generation (PVG) of a volatile species Ir (presumably iridium tetracarbonyl hydride) for subsequent detection by inductively coupled plasma mass spectrometry (ICPMS). A thin-film flow-through photoreactor, operated in flow injection mode, provided high efficiency following optimization identified key PVG parameters, notably, irradiation time, pH reaction medium, and presence metal sensitizers. For routine use analytical...

Photochemical vapor generation (PVG) of Mo was accomplished using a 19 W high-efficiency flow-through photoreactor operating in flow injection mode 30–50% (w/v) formic acid as reaction medium. The generated volatile product (most probably molybdenum hexacarbonyl) directed by an argon carrier gas to plastic gas–liquid separator and introduced into the spray chamber inductively coupled plasma mass spectrometer for detection. Particular attention paid determination overall PVG efficiency...

This work describes the method of a selective hydride generation-cryotrapping (HG-CT) coupled to an extremely sensitive but simple in-house assembled and designed atomic fluorescence spectrometry (AFS) instrument for determination toxicologically important As species. Here, advanced flame-in-gas-shield atomizer (FIGS) was interfaced HG-CT its performance compared standard miniature diffusion flame (MDF) atomizer. A significant improvement both in sensitivity baseline noise found that...

Efficient photochemical vapor generation (PVG) of tungsten has been achieved for the first time using a 19 W thin film flow-through photoreactor. The volatile product (most probably hexacarbonyl) was generated flow injection mode and 40% (v/v) formic acid as reaction medium. An inductively coupled plasma mass spectrometer utilized ultrasensitive detection. addition Cd2+ sensitizer critical, enhancing overall PVG efficiency some 30 000-fold. At an optimal irradiation s, 6.1-fold enhancement...

Herein, we report on surprisingly efficient photochemical vapor generation (PVG) of Ru, Re, and especially Ir, achieved from very dilute HCOOH media employing a thin-film flow-through photoreactor operated in flow injection mode. In the absence added metal ion sensitizers, efficiencies near 20% for Ir approximately 0.06% Ru Re occur narrow range concentrations (around 0.01 M), significantly higher than previously reported conventionally optimized (1-20 M). A substantial enhancement...

A sensitive method for Rh determination was developed by coupling photochemical vapor generation (PVG) sample introduction to inductively coupled plasma mass spectrometry (ICPMS). PVG conducted in a thin-film flow-through photoreactor operated flow injection mode from medium comprising 10 M HCOOH. efficiency substantially enhanced the addition of mg L–1 Cu2+ and 5 Co2+ as mediators well 50 mM NaNO3. The volatile product (likely Rh(CO)4H) found be less stable when prolonged contact with...

An ultra-sensitive method for arsenic (As) speciation analysis based on selective hydride generation (HG) with preconcentration by cryotrapping (CT) and inductively coupled plasma-mass spectrometry (ICP-MS) detection is presented. Determination of the valency As species performed HG without prereduction (trivalent only) or L-cysteine (sum tri- pentavalent species). Methylated are resolved basis thermal desorption formed methyl substituted arsines after collection at −196 °C. Limits 3.4,...

Using hydride generation for the determination of inorganic arsenic in rice gives same result as HPLC.

A method for analysis of toxicologically important arsenic species in blood plasma and whole by selective hydride generation with cryotrapping (HG-CT) coupled either to atomic absorption spectrometry (AAS) a quartz multiatomizer or inductively mass (ICPMS) has been validated. Sample preparation, which involved only 5 times dilution addition Triton X-100, Antifoam B, l-cysteine, suppressed excessive foaming generator. Calibration slopes spiked arsenate, monomethylarsonate, dimethylarsinate at...

An experimental setup consisting of a flow injection hydride generator coupled to an atomic fluorescence spectrometer was optimized in order generate arsanes from tri- and pentavalent inorganic arsenic species (iAsIII, iAsV), monomethylarsonic acid (MAsV), dimethylarsinic (DMAsV) with 100% efficiency the use only HCl NaBH4 as reagents. The optimal concentration 2 mol L–1; 2.5% (m/v), volume reaction coil 8.9 mL. To prevent excessive signal noise due fluctuations supply atomizer, new design...

An extremely sensitive methodology for the determination of Ru was developed by coupling photochemical vapor generation (PVG) analyte introduction with inductively coupled plasma mass spectrometry (ICPMS). PVG undertaken a thin-film flow-through photoreactor in medium comprising 8 M formic acid presence 10 mg L–1 Co2+ and 25 Cd2+. The volatile product (presumably ruthenium pentacarbonyl) generated flow injection mode, yielding an overall efficiency 29% at sample rate 1.4 mL min–1. both Cd2+...

A methodology for cadmium determination at ultratrace levels based on chemical vapour generation (CVG) coupled to atomic fluorescence spectrometry (AFS) was developed.

The generation of an analytically useful volatile form Au has been studied. flow injection was performed in a dedicated generator consisting special mixing apparatus and gas–liquid separator design the presence surfactants (Triton X-100, Antifoam B) diethyldithiocarbamate. on-line atomization quartz tube multiatomizer for atomic absorption (AAS) detection employed as convenient atomization/detection means. optimization conditions resulted analytical procedure yielding limit 17 ng ml−1 very...

A study of a transport process and interferences in the method Ag chemical vapor generation (CVG) with AAS detection was performed. modified externally heated quartz multiatomizer inlet arm designed to minimize losses. Both efficiency spatial distribution residual analyte an apparatus were studied by means 111Ag radioactive indicator. Compared our previous design significantly modified: removal spray chamber heating 300 °C allowed us reduce losses from 65% 4% thus improve overall CVG up...

UV-photochemical generation of cadmium volatile species was carried out from formic acid medium containing ferrous ions resulting in improved reproducibility.