A5100455750- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Catalytic Processes in Materials Science
- Perovskite Materials and Applications
- Conducting polymers and applications
- Polyoxometalates: Synthesis and Applications
- Organic Electronics and Photovoltaics
- Advanced Photocatalysis Techniques
- Advanced ceramic materials synthesis
- Advanced Fiber Optic Sensors
- Luminescence and Fluorescent Materials
- Quantum Dots Synthesis And Properties
- Nanocluster Synthesis and Applications
- Muscle activation and electromyography studies
- Carbon dioxide utilization in catalysis
- Metal complexes synthesis and properties
- Lanthanide and Transition Metal Complexes
- Molecular Sensors and Ion Detection
- Electrocatalysts for Energy Conversion
- Supramolecular Chemistry and Complexes
- Photonic and Optical Devices
Chinese Academy of Sciences
2016-2025
Fujian Institute of Research on the Structure of Matter
2016-2025
Key Laboratory of Guangdong Province
2019-2025
Southern Medical University
2019-2025
Kunming University of Science and Technology
2017-2025
Chengdu University of Technology
2025
Nanchang Hangkong University
2021-2025
Shanghai Tenth People's Hospital
2020-2025
North China University of Science and Technology
2024-2025
Dongguan People’s Hospital
2025
Carbon dots show potential in lighting and displays. However, only their fluorescence has been observed so far. Here we report the observation of phosphorescence from carbon a polyvinyl alcohol matrix. The is attributed to CO bonds on surface very long lifetime (∼380 ms).
Mononuclear Cu I complexes with mixed ligands are used to fabricate green phosphorescent organic light‐emitting diodes. The electroluminescence (EL) maximum at 524 nm coincides well its photoluminescent (PL) spectrum in poly(methyl methacrylate) film (see Figure). A current efficiency of 10.5 cd –1 105 m –2 and a brightness up 1663 demonstrated.
Catalytic cavities: Hybrid zeolitic imidazolate frameworks (HZIFs) integrate compositional and structural features of inorganic zeolites (ZIFs). The combination catalytically active TO4 tetrahedra with zinc–imidazolate units leads to a new kind porous material distinct framework topology, unusual high thermal stability, catalytic properties. Detailed facts importance specialist readers are published as "Supporting Information". Such documents peer-reviewed, but not copy-edited or typeset....
A doping strategy was successfully applied to tune the gas sorption and photocatalytic properties of a microporous material ZIF-67. The Cu-doped phase integrated both structural features functions ZIF-67 showed high uptake capacity highly efficient visible-light-driven property on degradation methyl orange.
Abstract Ultrathin, molecular sieving membranes composed of microporous materials offer great potential to realize high permeances and selectivities in separation applications, but strategies for their production have remained a challenge. Here we show route the scalable nanometre-thick metal–organic framework (MOF) membranes, specifically via gel–vapour deposition, which combines sol–gel coating with vapour deposition solvent-/modification-free precursor-/time-saving synthesis. The uniform...
A conjugated small molecule containing a benzodithiophene unit shows high performance in bulk heterojunction (BHJ) solar cells. Using the simple solution spinning process, PCE is achieved by employing this as donor BHJ Detailed facts of importance to specialist readers are published "Supporting Information". Such documents peer-reviewed, but not copy-edited or typeset. They made available submitted authors. Please note: The publisher responsible for content functionality any supporting...
From a basic tetrahedral Cu(4)I(4) cluster, new MTN-type cluster-organic framework (COZ-1) containing giant 6(4)5(12) and 5(12) cages was successfully constructed. The cage has an inner diameter of 2.6 nm large pore volume 9.2 nm(3); these clusters with bulky size offer opportunities for not only the formation 4-connected zeotype structures but also integration porosity photoluminescent properties from both cluster framework.
Photocatalytic reduction of CO2 to value-added fuel has been considered be a promising strategy reduce global warming and shortage energy. Rational design synthesis catalysts maximumly expose the active sites is key activate molecules determine reaction selectivity. Herein, we synthesize well-defined copper-based boron imidazolate cage (BIF-29) with six exposed mononuclear copper centers for photocatalytic . Theoretical calculations show single Cu site including weak coordinated water...
We present the formation of largest titanium-oxo cluster, [Ti42(μ3-O)60(OiPr)42(OH)12)](6-), with first fullerene-like Ti-O shell structure. The {Ti42O60} core this compound exemplifies same icosahedral (Ih) symmetry as C60, highest possible for molecules. According to coordination environments, Ti centers in cluster can be arranged into a Platonic {Ti12} icosahedron and an Archimedean {Ti30} icosidodecahedron. solution stability was confirmed by electrospray ionization mass spectrometry....
A water-stable cationic MOF could be used as a single crystal container to capture Cr(vi)-oxyanions via ion exchange with high capacity and selectivity. It is the first report that demonstrates CrO42- ions traced confirmed single-crystal (SC-SC) pattern.
Photocatalytic conversion of methane to value-added products under mild conditions, which represents a long sought-after goal for industrial sustainable production, remains extremely challenging afford high production and selectivity using cheap catalysts. Herein, we present the crystal phase engineering commercially available anatase TiO2 via simple thermal annealing optimize structure-property correlation. A biphase catalyst with (90%) rutile (10%) optimal interface concentration exhibits...
Chemodynamic therapy (CDT) is an emerging strategy for cancer treatment based on Fenton chemistry, which can convert endogenous H2O2 into toxic ·OH. However, the limited endocytosis of passive CDT nanoagents with low penetrating capability resulted in unsatisfactory anticancer efficacy. Herein, we propose successful fabrication a self-propelled biodegradable nanomotor system hollow MnO2 nanoparticles catalytic activity active Fenton-like Mn2+ delivery and enhanced CDT. Compared counterparts,...
Abstract Atomically dispersed 3D transitional metal active sites with nitrogen coordination anchored on carbon support have emerged as a kind of promising electrocatalyst toward oxygen reduction reaction (ORR) in the field fuel cells and metal–air cells. However, it is still challenge to accurately modulate structure single‐atom sites, especially first‐shell coordination, well identify relationship between geometric/electronic ORR performance. Herein, carbon‐supported nickel catalyst...
Abstract While significant efforts in surface engineering have been devoted to the conversion process of lead iodide (PbI 2 ) into perovskite and top layer with remarkable progress, exploration residual PbI clusters hidden bottom on limited. In this work, a new strategy involving 1‐butyl‐3‐methylimidazolium acetate (BMIMAc) ionic liquid (IL) additives is developed it found that both cations anions ILs can interact components, thereby regulating crystallization diminishing residue as well...
Abstract Layered double hydroxides (LDHs), promising bifunctional electrocatalysts for overall water splitting, are hindered by their poor conductivity and sluggish electrochemical reaction kinetics. Herein, a hierarchical Cu‐doped NiCo LDH/NiCo alloy heterostructure with rich oxygen vacancies electronic modulation is tactfully designed. It extraordinarily effectively drives both the evolution (151 mV@10 mA cm −2 ) hydrogen (73 in an alkaline medium. As electrodes low cell voltage of 1.51 V...
Owing to the electrical conductivity and periodic porosity, conductive metal–organic framework (cMOF) ultrathin films open new perspectives photocatalysis. The space-selective assembly of catalytic sites photosensitizers in/on cMOF is favorable for promoting separation photogenerated carriers mass transfer. However, controllable integration functional units into film rarely reported. Herein, via synergistic effect steric hindrance an electrostatic-driven strategy, dinuclear-metal molecular...
Abstract Organic solar cells (OSCs) have emerged as a promising solution for sustainable energy production, offering advantages such low carbon footprint, short payback period, and compatibility with eco‐solvents. However, the use of hazardous solvents continues to dominate best‐performing OSCs, mainly because challenges controlling phase separation domain crystallinity in In this study, we combined solvent vapor treatment CS 2 thermal annealing precisely control PM6:M‐Cl PM6:O‐Cl systems...