Hanrui Zhang

ORCID: 0000-0001-8576-9705
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About
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Research Areas
  • Advancements in Battery Materials
  • Advanced Battery Materials and Technologies
  • Advanced Battery Technologies Research
  • Extraction and Separation Processes
  • Microbial Fuel Cells and Bioremediation
  • Conducting polymers and applications
  • Wastewater Treatment and Nitrogen Removal
  • Fluid Dynamics and Mixing
  • Membrane-based Ion Separation Techniques
  • Flow Measurement and Analysis
  • Advanced materials and composites
  • Advancements in Transdermal Drug Delivery
  • Recycling and Waste Management Techniques
  • Advanced ceramic materials synthesis
  • Laser Applications in Dentistry and Medicine
  • Water Treatment and Disinfection
  • Lipid Membrane Structure and Behavior
  • Gas Sensing Nanomaterials and Sensors
  • MXene and MAX Phase Materials
  • Advanced battery technologies research
  • Rheology and Fluid Dynamics Studies
  • Dermatologic Treatments and Research
  • Supercapacitor Materials and Fabrication
  • Electrical and Bioimpedance Tomography
  • Advanced Drug Delivery Systems

Pennsylvania State University
2024-2025

National University of Singapore
2025

Shanghai Ninth People's Hospital
2025

Shanghai Jiao Tong University
2025

Tianjin University
2020-2023

Chinese Academy of Sciences
2005-2022

Shaanxi University of Science and Technology
2022

Columbia University
2019-2022

Research Center for Eco-Environmental Sciences
2022

Technical Institute of Physics and Chemistry
2020

Abstract Solid‐state lithium‐metal batteries with solid electrolytes are promising for next‐generation energy‐storage devices. However, it remains challenging to develop that both mechanically robust and strong against external mechanical load, due the brittleness of ceramic softness polymer electrolytes. Herein, a nacre‐inspired design ceramic/polymer composite “brick‐and‐mortar” microstructure is proposed. The nacre‐like electrolyte (NCPE) simultaneously possesses much higher fracture...

10.1002/adma.201905517 article EN Advanced Materials 2019-11-29

Solid polymer electrolytes (SPEs) are attractive for next-generation energy storage, because they more thermally stable compared to conventional liquid and simpler scalable manufacturing than ceramic electrolytes. However, there is a growing body of research suggesting that the interfacial instabilities between SPEs other battery components (e.g., electrodes electrolyte fillers) hinder their practical applications. This Perspective highlights degradation mechanisms at these interfaces...

10.1021/acsenergylett.0c01465 article EN ACS Energy Letters 2020-09-14

Abstract With the rapid increase in lithium consumption for electric vehicle applications, its price soared during past decade. To secure a reliable and cost-effective supply chain, it is critical to unlock alternative extraction resources beyond conventional brine. In this study, we develop an electrochemical method directly leach from α-phase spodumene. We find H 2 O promoter can significantly reduce leaching potential by facilitating electron transfer changing reaction path. Upon...

10.1038/s41467-024-48867-0 article EN cc-by Nature Communications 2024-06-13

Traditional Li-ion intercalation chemistry into graphite anodes exclusively utilizes the cointercalation-free or cointercalation mechanism. The latter mechanism is based on ternary compounds (t-GICs), where glyme solvents were explored and proved to deliver unsatisfactory cyclability in LIBs. Herein, we report a novel mechanism, that is, situ synthesis of t-GIC tetrahydrofuran (THF) electrolyte via spontaneous, controllable reaction between binary-GIC (b-GIC) free THF molecules during...

10.1021/jacs.4c04594 article EN cc-by Journal of the American Chemical Society 2024-06-07

Keloids are a typical skin fibroproliferative disease that can cause severe aesthetic and functional concerns. Pain pruritus the most common clinical symptoms of keloids, but mechanisms underlying these remain unclear. The peripheral nervous system plays pivotal role in transmission superficial sensation signals. Mounting evidence has shown potential correlations between disturbance pain keloids. Here, we summarize neurological dysfunction development pruritus, with specific focus on...

10.3390/biomedicines13030663 article EN cc-by Biomedicines 2025-03-08

Designing the solid–electrolyte interphase (SEI) is critical for stable, fast-charging, low-temperature Li-ion batteries. Fostering a “fluorinated interphase,” SEI enriched with LiF, has become popular design strategy. Although LiF possesses low conductivity, many studies have reported favorable battery performance fluorinated SEIs. Such contradiction suggests that optimizing must extend beyond chemical composition to consider spatial distributions of different species. In this work, we...

10.1073/pnas.2420398122 article EN cc-by-nc-nd Proceedings of the National Academy of Sciences 2025-03-24

The electrode-electrolyte interface governs the kinetics and reversibility of all electrochemical processes. While theoretical models can calculate simulate structure associated properties this intriguing component, their validation by direct experimental measurement has been a long-standing challenge. Electrocapillarity is classical technique that derives interfacial through potential-dependent surface tensions, but its limited resolution confined application to ideal systems such as...

10.1021/jacs.4c03791 article EN Journal of the American Chemical Society 2024-07-16

Iron fluoride compounds offer an exciting pathway toward low-cost and high-capacity conversion-type lithium-ion battery (LIB) cathodes. However, due to the sluggishness of electronic ionic transport in iron fluorides, mass loadings active materials previous studies are typically less than 2.5 mg cm–2, which is too low for practical applications. Herein, we improve charge electrodes at both nano- mesoscales enable high-mass-loading electrodes. At nanoscale, prepare electronically conducting...

10.1021/acsami.0c09185 article EN ACS Applied Materials & Interfaces 2020-07-02

Meeting the increasing demand for lithium in vehicle electrification and renewable energy storage requires innovations lithium-ion (Li+) separations. Traditional solar evaporation methods recovery are slow consume tremendous volumes of water secondary chemicals (acids bases). This study introduces a bipolar membrane capacitive deionization (BPM-CDI) unit direct extraction (DLE) LiOH production without external addition acids bases. Utilizing de-lithiated lithium-iron-phosphate (LFP) coated...

10.26434/chemrxiv-2024-2w9ph preprint EN cc-by-nc-nd 2024-05-06

Designed growth of zinc oxide (ZnO)/poly(3,4‐ethylenedioxythiophene) (PEDOT) core/shell hybrid nanotube arrays has been achieved by electropolymerization technique. The ZnO/PEDOT nanotubes electropolymerized for 2000‐second display enhanced electrochromic properties the contrast ratio up to 31.3%, a lot higher than those pure PEDOT and nanorods. Moreover, coloring efficiency increases from 105.2 cm 2 C −1 nantotube with electrodeposition time 1000 seconds 122.2 2000 at 520 nm. Therefore,...

10.1002/sia.6746 article EN Surface and Interface Analysis 2020-01-21

Meeting the increasing demand for lithium in vehicle electrification and renewable energy storage requires innovations lithium-ion (Li + ) separations. Traditional solar evaporation methods recovery are slow consume tremendous volumes of water secondary chemicals (acids bases). This study introduces a bipolar membrane capacitive deionization (BPM-CDI) unit direct extraction LiOH production without external addition acids bases. Utilizing de-lithiated lithium-iron-phosphate (LFP) coated...

10.1149/1945-7111/ad7a25 article EN cc-by-nc-nd Journal of The Electrochemical Society 2024-09-12

With the rapid increase in lithium consumption for electric vehicle applications, its price soared during past decade. To secure a reliable and cost-effective supply chain, it's critical to unlock alternative resources extraction, beyond conventional brine. In this study, we developed an electrochemical method directly leach from solid-state α-phase spodumene. We found H 2 O promoter can significantly reduce leaching potential by facilitating electron transfer changing reaction path. Upon...

10.1149/ma2024-02252017mtgabs article EN Meeting abstracts/Meeting abstracts (Electrochemical Society. CD-ROM) 2024-11-22

The stripping reaction of lithium will greatly impact the cyclability and safety Li metal batteries. However, pits' nucleation growth, origin uneven stripping, are still poorly understood. In this study, we analyze mechanism pits their morphology evolution with a large population electrode area (>0.45 cm 2 ). We elucidate dependence pit size density on current overpotential, which is aligned classical theory. With laser scanning confocal microscope, reveal preferential certain crystal...

10.1149/ma2024-0271004mtgabs article EN Meeting abstracts/Meeting abstracts (Electrochemical Society. CD-ROM) 2024-11-22

Nanoscale zero-valent iron (nZVI) coupled denitrification is considered the typical abiotic-biotic synergistic process, but its underlying electron transfer mechanism remains unclear. Herein, we performed a heavy water labeling single-cell Raman spectroscopy (D 2 O-SCRS) for in-situ and dynamic characterization of Cytochrome c-mediated process with coexisting nZVI model denitrifying bacterium. Interestingly, resulted in strong effect high efficiency 99.8% (~100 mg L -1 NO 3 -N),...

10.2139/ssrn.4227532 article EN SSRN Electronic Journal 2022-01-01
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