A novel atmospheric pressure glow discharge generated in contact with a flowing liquid anode (FLA-APGD) was developed as the efficient excitation source for optical emission spectrometry (OES) detection. Differences appearance and electrical characteristic of FLA-APGD conventional system operated cathode (FLC-APGD) were studied detail discussed. Under optimal operating conditions FLA-APGD, from analytes (Ag, Cd, Hg, Pb, Tl, Zn) 20 to 120 times higher compared FLC-APGD. Limits detections...

Miniaturized atmospheric pressure glow discharges (APGDs) were generated in contact with small sized flowing liquid cathode systems. As anodes a solid pin electrode or miniature flow Ar microjet applied. Both discharge systems operated the open to air atmosphere. Hydrogen peroxide (H2O2) as well ammonium (NH4 +), nitrate (NO3 −), and nitrite (NO2 −) ions quantified solutions treated by studied Additionally, an increase acidification of these was noted each case. Emission spectra near zone...

A novel liquid drop anode (LDA) direct current atmospheric pressure glow discharge (dc-APGD) system was applied for determination of Cd in microsamples (50 μL) by optical emission spectrometry (OES). The microdischarge generated open-to-air atmosphere between a solid pin type tungsten cathode and placed on graphite disk anode. arrangement the PTFE chip platform as well simple robust. limit detection (LOD) developed LDA-APGD-OES method 0.20-0.40 μg L-1, while precision (as relative standard...

This study presented a straightforward method for detecting the adulteration of natural bee honey with consumable artificial and syrups. The approach, based on measuring alkali alkaline earth metal content, revealed that adulterated samples had lower K, Rb, Mg, Ca levels elevated Na content. A novel cost-effective method, solution cathode glow discharge optical emission spectrometry (SCGD OES), was developed elemental analysis. method's trueness confirmed through ICP OES MS measurements....

Miniaturized atmospheric pressure glow discharge with a flowing liquid cathode was used for the elemental analysis (Ca, Cu, Fe, K, Li, Mg, Mn, Na, Rb and Zn) of honeys by OES. A simplified sample preparation procedure proposed samples were only dissolved in water acidified HCl.

Novel atmospheric pressure glow discharge (APGD) plasma systems, sustained between a miniaturized flowing liquid anode (FLA) or cathode (FLC) and He nozzle jet, were investigated for the determination of Bi by optical emission spectrometry (OES).

A direct current atmospheric pressure glow discharge generated in contact with a flowing liquid cathode was used to study the effect of concentration two non-ionic surfactants, i.e., Triton x-45 and x-405 added electrolyte solutions, on emission characteristic excitation source by using optical spectrometry. The intensity different molecular atomic species as well background level were measured. Selected spectroscopic parameters, rotational temperatures OH N2 molecules, Co H atoms, electron...

Gold nanoparticles (Au NPs) were prepared by direct current atmospheric pressure glow microdischarge (dc-μAPGD) generated between a miniature argon flow microjet and flowing liquid cathode. The applied discharge system was operated in continuous mode. influence of various stabilizers added to the solution cathode, i.e., gelatin (GEL), polyvinylpyrrolidone (PVP), or polyvinyl alcohol (PVA), as well concentration Au precursor (chloroauric acid, HAuCl4) on production growth NPs investigated....

A technique of vapor generation assisted by a microplasma was used for sample introduction into inductively coupled plasma optical emission spectrometry (ICP OES). Replacing pneumatic nebulizer with novel device improved the sensitivities analytical signals Ag, Bi, Cd, Pb, Tl, and Zn (by 2–13 times), as well concomitant reduction in their detection limits (DLs). Moreover, an outstanding improvement (30-fold) achieved Hg. The factors contributing to boosted signal intensities were higher...

Low power direct current atmospheric glow microdischarges were sustained between miniature Ar or He flow nozzle microjets and a small-sized flowing liquid cathode as new excitation microsources for optical emission spectrometry. The morphology of spectra both was compared the effect rate gases on their performance characteristic related to molecular bands atomic lines selected metals (Ca, Cd, Cu, Fe, K, Li, Mg, Mn, Na Zn) studied using It established that in microdischarge with microjet...

A direct current atmospheric pressure glow discharge operated between a pin-type solid metallic electrode and the surface of flowing solution, positively or negatively charged serving as liquid anode cathode, was used for synthesizing gold nanoparticles.

Introduction of Hg vapor to μAPGD formed between a miniature He flow microjet and flowing liquid cathode resulted in significant improvement the sensitivity I 253.7 nm emission line sub-ppb DL Hg.

The direct determination of 18 elements (B, Ba, Ca, Cd, Cs, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Rb, Sr, Tl, and Zn) in 1% aqueous honey solutions (dilution factor = 100) by ICP MS was presented. presence sugar sample caused a decrease analytical signals, the appearance carbon-containing polyatomic ions, deposition carbonaceous products on sampler cone. On flip side, these effects did not destabilize ICP, while internal standard calibration (9Be, 89Y, 153Eu as standards) made it possible to...