Raphaela Azevedo Rafael

ORCID: 0000-0001-8913-8361
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About
Contact & Profiles
Research Areas
  • Catalysis and Hydrodesulfurization Studies
  • Catalysis for Biomass Conversion
  • Lignin and Wood Chemistry
  • Advanced Photocatalysis Techniques
  • TiO2 Photocatalysis and Solar Cells
  • Catalytic Processes in Materials Science
  • Catalysts for Methane Reforming
  • Biofuel production and bioconversion
  • Iron oxide chemistry and applications
  • Clay minerals and soil interactions
  • Asymmetric Hydrogenation and Catalysis
  • Gas Sensing Nanomaterials and Sensors
  • Pigment Synthesis and Properties
  • Nanomaterials for catalytic reactions
  • Chemical Synthesis and Reactions
  • Layered Double Hydroxides Synthesis and Applications

Unité de catalyse et de chimie du solide de Lille
2023-2024

École Centrale de Lille
2023-2024

Université de Lille
2023-2024

Université d'Artois
2023-2024

Centre National de la Recherche Scientifique
2023-2024

Catalyse
2023

Military Institute of Engineering
2020

Rio de Janeiro Federal Institute of Education, Science and Technology
2019

Instituto Nacional de Tecnologia
2019

Abstract Bio‐oil obtained from the depolymerization of lignocellulosic biomass is a potential alternative source to replace fossil fuels. However, due high oxygen content, bio‐oil must be upgraded. In this direction, hydrodeoxygenation reaction (HDO) widely applied. Considering complex chemical composition bio‐oil, variety model molecules have been used in literature study mechanism HDO process. work, we discuss heterogeneous catalysts and conditions (temperature, pressure, solvent)...

10.1002/cctc.202300486 article EN ChemCatChem 2023-07-20

Materials exhibiting different textural and surface properties (SiO 2 , TiO ZrO ZSM-5) were investigated as supports for Mo carbides in the upgrading of furfural (FF) liquid phase to produce 2-methylfuran (2MF).

10.1039/d4ra04256e article EN cc-by-nc RSC Advances 2024-01-01

The effect of metal and support acidity on the hydroconversion dimeric aryl ethers, used as model molecules for lignin, is still under debate, both in terms hydrogenolysis (cleavage ether bond) formation by-products (coupling aromatic monomers to dimers by alkylation reaction). Their role investigated here conversion three typical representative α-O-4, β-O-4, 4-O-5 linkages respectively, benzyl phenyl (BPE), phenethoxybenzene (PEB), diphenyl (DPE), at 503 K, 18 bar H2 decalin. Ru- Pd-based...

10.3390/catal13040783 article EN Catalysts 2023-04-21

This work investigates the role of support and metal particle size in performance Pd-based catalysts for hydroconversion benzyl phenyl ether (BPE) liquid phase. supported on different oxides (SiO2, TiO2, Nb2O5, Al2O3, ZrO2, HZSM5) were synthesized by incipient wetness impregnation (particle > 4 nm) sol-immobilization methods < nm). Different reaction pathways leading to aromatics, polyaromatics, or cycloalkanes have been evidenced, acidity competition between these has clarified. The acid...

10.1021/acssuschemeng.3c02633 article EN ACS Sustainable Chemistry & Engineering 2023-09-27

Abstract The hydrodeoxygenation of furfural (FF) over Mo carbides in liquid phase at 200 °C, 30 bar H 2 for 4 h 2‐butanol was investigated. Unsupported and SiO ‐supported carbide with different crystallographic phases (β‐Mo C/SiO α‐MoC/SiO ), the presence Cu Ni as promoters were studied. reactivation treatment under atmosphere passivated investigated by XAS. results show that is present states oxidation catalysts, more severe bimetallic systems, which original are not restored after...

10.1002/cctc.202300890 article EN ChemCatChem 2023-10-20
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