A5005215893- Metal-Organic Frameworks: Synthesis and Applications
- Zeolite Catalysis and Synthesis
- Chemical Synthesis and Characterization
- X-ray Diffraction in Crystallography
- Mesoporous Materials and Catalysis
- Crystallization and Solubility Studies
- Catalytic Processes in Materials Science
- Adsorption and Cooling Systems
- Crystal Structures and Properties
- Polyoxometalates: Synthesis and Applications
- Crystallography and molecular interactions
- Magnetism in coordination complexes
- Phase Change Materials Research
- Carbon Dioxide Capture Technologies
- Covalent Organic Framework Applications
- Adsorption and biosorption for pollutant removal
- Thermal and Kinetic Analysis
- Advanced NMR Techniques and Applications
- Advanced Photocatalysis Techniques
- Catalysis and Oxidation Reactions
- Genetic Neurodegenerative Diseases
- Membrane Separation and Gas Transport
- Catalysis and Hydrodesulfurization Studies
- Advancements in Battery Materials
- Advanced Battery Materials and Technologies
National Institute of Chemistry
2016-2025
University of Nova Gorica
2016-2025
School Centre Nova Gorica
2017
University of Ljubljana
1995-2016
Community Health Centre Ljubljana
2013-2015
University of Zagreb
2011-2013
Institute for Development and International Relations
2013
Croatian Personal Data Protection Agency
2013
Jožef Stefan Institute
2010
Laboratoire Catalyse et Spectrochimie
2008
Hydrophilic porous materials are recognized as very promising for water‐sorption‐based energy storage and transformation. In this study, a porous, zeolite‐like aluminophosphate with LTA (Linde Type A) topology is inspected an energy‐storage material. The study motivated by the material's high predicted pore volume. According to sorption calorimetric tests, outperforms all other metal‐organic tested so far. It adsorbs water in extremely narrow relative‐pressure interval (0.10 < p / 0 0.15)...
Abstract The utilization of the reversible chemical and physical sorption water on solids provides a new thermal energy storage concept with great potential for lossless long‐term storage. performance microporous aluminophosphates in heat applications is highlighted by comparative thermogravimetric calorimetric study three known materials (SAPO‐34, AlPO 4 ‐18, APO‐Tric) correlated their structural features. maximum capacity similar all samples results stored density 240 kWh m −3 40–140 °C...
A two-step procedure for preparation of LiMnPO4 with small particle size (15–20 nm) and embedded in a carbon matrix is presented. The crucial point that prevents excessive growth the avoidance lithium first firing step, so Mn2P2O7 particles are obtained. Because matrix, also cannot grow second which involves lithiation heating to 700 °C argon. prepared shows high theoretical capacity (up 95% value) stable cycling (>130 mAh/g, even after 100 cycles at 55 rate C/20). At room temperature using...
Structural dynamics of Ca(BDC)(DMF)(H2O) with rhombic-shaped channels and 44 net topology upon heating hydration were elucidated by using complementary methods diffraction (XRD) spectroscopy (FT-IR, MAS NMR, EXAFS, XANES). During the framework underwent structural changes in two steps. The first change at 150 °C includes breaking Ca–O bonds H2O DMF molecules. In this step, is removed from surface or near crystals. affected parts crystals are transformed to a new nonporous Ca-BDC(400) phase...
The high structural and compositional flexibility of metal–organic frameworks (MOFs) shows their great potential for CO2 capture utilization in accordance with the environmental guidelines low-carbon technology developments. HKUST-1 as one most intensively studied representatives MOFs such purposes excels because its simplicity production ability to tune intrinsic properties by various functionalization processes. In present work, ethylenediamine was performed first time order thoroughly...
Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). The resulting HIPEs containing the MIL-100(Fe) (MIL: Materials of Institut Lavoisier) at interface between oil- and water-phases then cured, 100 μm thick, fully open, hierarchically porous hybrid membranes obtained. properties MIL-100(Fe)@pDCPD polyHIPE characterized it is found that up 14 wt%...
The spatial distribution of different linkers within mixed-linker metal-organic frameworks crucially influences the properties such materials. A simple and robust approach based on (1)H spin-diffusion magic-angle-spinning nuclear magnetic resonance measurements modeling curves is presented; this facilitates distinction between homogeneous clustered distributions. performance demonstrated with an example aluminum-based material DUT-5, which has framework consisting biphenyl bipyridyl...
A HKUST-1 metal–organic framework was crystallized in the NH<sub>2</sub>-modified mesostructured silica FDU-12 order to improve its structural stability upon water exposure.
Currently, metal–organic framework (MOF)–polymer composites are attracting great interest as a step forward in making MOFs useful material for industrially relevant applications. However, most of the research is engaged with finding promising MOF/polymer pairs and less synthetic methods by which these materials then combined, albeit hybridization has significant impact on properties new composite macrostructure. Thus, focus this work innovative polymerized high internal phase emulsions...
A γ-alumina support functionalized with transition metals is one of the most widely used industrial catalysts for total oxidation volatile organic compounds (VOCs) as air pollutants at higher temperatures (280-450 °C). By rational design a bimetal CuFe-γ-alumina catalyst, synthesized from dawsonite alumina precursor, activity in toluene model VOC lower temperature (200-380 °C) achieved. fundamental understanding catalyst and reaction mechanism elucidated by advanced microscopic spectroscopic...
Abstract Efficient CO 2 capture at concentrations between 400–2000 ppm is essential for maintaining air quality in a habitable environment and advancing carbon technologies. This study introduces NICS‐24 (National Institute of Chemistry Structures No. 24), Zn‐oxalate 3,5‐diamino‐1,2,4‐triazolate framework with two distinct square‐shaped channels, designed to enhance indoor‐relevant concentrations. exhibits uptake 0.7 mmol/g mbar 25 °C, significantly outperforming the compositionally related...
Four new magnesium 1,3,5-benzenetricarboxylate metal–organic framework materials (NICS-n; n = 3–6) were synthesized solvothermally in the presence of solvents with different EtOH/H2O ratios. We showed that crystallization process Mg–1,3,5-benzentricarboxylate system strongly depends on solvent composition, and dimensionality their structures can be tuned by changing EtOH/water ratios reaction mixture. The only water as a yields zero-dimensional molecular structure Mg(H2BTC)2(H2O)4 (NICS-3)....
Abstract The synthesis of phase‐pure Co‐ZIF‐9, an important cobalt‐based zeolitic imidazolate framework, could be achieved by modification the reported procedure through pH adjustment starting mixture. Co‐ZIF‐9 material obtained has been characterized a combination UV/Vis, FTIR, and Raman spectroscopy as well thermogravimetric analysis (TGA) XRD possesses lower overall crystallinity. This can explained addition base for method. On basis these findings, pathway formation secondary phase,...
HKUST-1(Cu) and MOF-5(Zn)@polyHIPE hybrid materials were prepared using a metal salt-free technique, wherein metal–organic frameworks <italic>in situ</italic> generated from the CuO- ZnO-nanoparticles through secondary recrystallization.
Improved performance of modified binder-free zeolite Y in mobile sorption heat storage for low-temperature industrial waste recovery.
Efficient CO2 capture at concentrations between 400‐2000 ppm is essential for maintaining air quality in a habitable environment and advancing carbon technologies. This study introduces NICS‐24 (National Institute of Chemistry Structures No. 24), Zn‐oxalate 3,5‐diamino‐1,2,4‐triazolate framework with two distinct square‐shaped channels, designed to enhance indoor‐relevant concentrations. exhibits uptake 0.7 mmol/g 2 mbar 25 °C, significantly outperforming the compositionally related...