A5011315409- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Organometallic Complex Synthesis and Catalysis
- Asymmetric Hydrogenation and Catalysis
- Synthetic Organic Chemistry Methods
- Carbon dioxide utilization in catalysis
- Coordination Chemistry and Organometallics
- Chemical Reactions and Isotopes
- Muon and positron interactions and applications
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Catalytic Cross-Coupling Reactions
- Cyclopropane Reaction Mechanisms
- Ferrocene Chemistry and Applications
- Catalytic C–H Functionalization Methods
Université Claude Bernard Lyon 1
2023-2025
École d'Ingénieurs en Chimie et Sciences du Numérique
2023-2025
Centre National de la Recherche Scientifique
2023-2025
Institut de Chimie
2025
A. N. Nesmeyanov Institute of Organoelement Compounds
2018-2024
D. Mendeleyev University of Chemical Technology of Russia
2018-2022
Russian Academy of Sciences
2021
The activation of C–H bonds by heterobimetallic compounds is a rich area research that has recently received increased attention. This perspective highlights recent advances and aims to guide the reader in this rapidly evolving field.
A Surface OrganoMetallic Chemistry (SOMC) approach is used to prepare a novel hafnium-iridium catalyst immobilized on silica, HfIr/SiO
The H/D exchange catalytic activity in (hetero)arenes of monometallic Ir and Os polydrides is boosted when paired with hafnium robust heterobimetallic complexes.
Abstract Grafting Ti(=N t Bu)(Me 2 Pyr) (py) (Me Pyr= 2,5‐dimethylpyrrolyl, py=pyridine) onto the surface of silica partially dehydroxylated at 700 °C gives well‐defined silica‐supported Ti imido complex (≡SiO)Ti(=N Pyr)(py) , which is fully characterized by IR and solid‐state NMR spectroscopy as well elemental mass balance analyses. While stoichiometric imido‐transfer reactivity typical for imides, obtained unique in that it enables catalytic transformations involving oxo intermediates. In...
We expand the series of well-defined silica-supported titanium imido complexes general formula (≡SiO)Ti(═NtBu)X(py)n prepared via surface organometallic chemistry in order to analyze effect X ligand on their catalytic properties. Two new complexes, (≡SiO)Ti(═NtBu)Cl(py)2 (2s) and (≡SiO)Ti(═NtBu)Cp(py) (3s), have been characterized with physicochemical techniques, performance oxo/imido heterometathesis other imido-transfer reactions has studied compared that previously reported catalyst...
We report the first examples of catalytic oxo/imido heterometathesis reactions that involve carboxylic acid derivatives (lactones).
Abstract A Surface OrganoMetallic Chemistry (SOMC) approach is used to prepare a novel hafnium‐iridium catalyst immobilized on silica, HfIr/SiO 2 , featuring well‐defined [≡SiOHf(CH t Bu) (μ‐H) 3 IrCp*] surface sites. Unlike the monometallic analogous materials Hf/SiO and Ir/SiO which promote n ‐pentane deuterogenolysis through C−C bond scission, we demonstrate that under same experimental conditions (1 bar D 250 °C, h, 0.5 mol %), heterobimetallic highly efficient selective for...
Abstract We report here the synthesis of 4‐coordinate Ti imido complexes Ti(=N t Bu)(OAr Bu ) 2 (py) ( and )(Me Pyr)(py) 3 (Ar = O ‐2,6‐ ‐4‐MeC 6 H , Me Pyr=2,5‐dimethylpyrrolyl) study their grafting onto surface partially dehydroxylated silica with aim to prepare aryloxide species. Study resulting materials IR, solid‐state NMR, elemental mass balance analyses demonstrates that bis ‐ complex leads a predominant formation silica‐supported amide (≡SiO)Ti(NH from protonation ligand silanols...
Zr imido chemistry: well-defined silica-supported complexes via Surface Organometallic Chemistry, oxo/imido heterometathesis and comparison with Ti analogs.
Abstract Grafting Ti(=N t Bu)(Me 2 Pyr) (py) (Me Pyr= 2,5‐dimethylpyrrolyl, py=pyridine) onto the surface of silica partially dehydroxylated at 700 °C gives well‐defined silica‐supported Ti imido complex (≡SiO)Ti(=N Pyr)(py) , which is fully characterized by IR and solid‐state NMR spectroscopy as well elemental mass balance analyses. While stoichiometric imido‐transfer reactivity typical for imides, obtained unique in that it enables catalytic transformations involving oxo intermediates. In...
ABSTRACT We report here the preparation and characterization of new well‐defined silica‐supported Ti imido complexes that present an L‐ligand variation in a structure currently most active oxo/imido heterometathesis catalyst (≡SiO)Ti(=N t Bu)(Me 2 Pyr)(py) ( 1s ), where py is replaced with stronger electron‐donating 4‐( N,N‐ dimethylamino)pyridine 2s ) or bidentate 2,2′‐bipyridine 3s ). The materials were characterized elemental mass balance analyses IR solid‐state NMR confirmed selective...