Alexander Krappe

ORCID: 0000-0001-9787-9637
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About
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Research Areas
  • Luminescence and Fluorescent Materials
  • Organic Light-Emitting Diodes Research
  • Family Business Performance and Succession
  • Photochemistry and Electron Transfer Studies
  • Supramolecular Chemistry and Complexes
  • Molecular Sensors and Ion Detection
  • Spectroscopy and Laser Applications
  • Perovskite Materials and Applications
  • Entrepreneurship Studies and Influences
  • Spectroscopy and Quantum Chemical Studies
  • Synthesis and Properties of Aromatic Compounds
  • Photochromic and Fluorescence Chemistry

Freie Universität Berlin
2019-2025

Witten/Herdecke University
2011

Purpose Family businesses (FBs) play an important role in economies across the world. FBs are consistently associated with specific attributes and expectations, which is something that points towards notion can be regarded as a “brand” on their own. The purpose of this paper to examine whether have actually become eyes wider population. Design/methodology/approach empirical investigation based “Personal Construct Theory” (PCT), developed by George R. Kelly. According theory, human beings...

10.1108/20436231111122272 article EN Journal of Family Business Management 2011-04-22

We report the synthesis of a fluorescent polycyclic aromatic hydrocarbon dye with "symmetry‐broken" core, derived from related hexa‐peri‐benzo¬coronene core fluoranthene subunit. The fluorophore is composed pure carbon skeleton without heteroatoms and exhibits remarkable photo¬luminescence properties photoluminescence quantum yield up to 67% in toluene, exceeding that parent hexa‐peri‐benzocoronene by factor 30. single crystal X‐ray structure reveals distorted structure, which responsible...

10.1002/chem.202500742 article EN Chemistry - A European Journal 2025-04-10

Fluorescent dyes are applied in various fields of research, including solar cells and light-emitting devices, as reporters for assays bioimaging studies. with an added high dipole moment pave the way to nonlinear optics polarity sensitivity. Redox activity makes it possible switch molecule's photophysical properties. Diaminodicyanoquinone derivatives possess moments, yet only low fluorescence quantum yields, have therefore been neglected fluorescent dyes. Here we investigate properties...

10.1002/anie.201903204 article EN Angewandte Chemie International Edition 2019-04-09

Molecular aggregation alters the optical properties of a system as fluorescence may be activated or quenched. This is usually described within well-established framework H- and J-aggregates. While H-aggregates show nonfluorescent blueshifted absorption bands with respect to isolated monomer, J-aggregates are fluorescent displaying redshifted peak. In this publication, we employ combined approach experiment theory study complex features photophysical diaminodicyanoquinone derivatives, which...

10.1021/acs.jpcb.1c01600 article EN The Journal of Physical Chemistry B 2021-04-21

Abstract In nature, molecular environments in proteins can sterically protect and stabilize reactive species such as organic radicals through non-covalent interactions. Here, we report a near-infrared fluorescent rotaxane which the stabilization of chemically labile squaraine fluorophore by coordination tetralactam macrocycle be controlled electrochemically. The switched between two co-conformations wheel either stabilizes or exposes fluorophore. Coordination affects squaraine’s stability...

10.1038/s42004-024-01312-1 article EN cc-by Communications Chemistry 2024-10-04

Abstract Fluoreszenzfarbstoffe werden in verschiedenen Forschungsbereichen eingesetzt, darunter Solarzellen, lichtemittierende Dioden, Reporter für Assays oder Bioimaging‐Studien. Ein zusätzliches hohes Dipolmoment ebnet den Weg zu nichtlinearer Optik und Polaritätsempfindlichkeit. Die Redoxaktivität ermöglicht es zudem, photophysikalische Eigenschaften der Moleküle verändern. Diaminodicyanochinon‐Derivate besitzen hohe Dipolmomente, aber nur geringe Fluoreszenzquantenausbeuten galten daher...

10.1002/ange.201903204 article DE Angewandte Chemie 2019-04-09
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