Tamilarasan Palanisamy

ORCID: 0000-0001-9957-8440
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About
Contact & Profiles
Research Areas
  • Electrochemical Analysis and Applications
  • Electrocatalysts for Energy Conversion
  • Gold and Silver Nanoparticles Synthesis and Applications
  • Analytical Chemistry and Sensors
  • Fuel Cells and Related Materials
  • Advancements in Battery Materials
  • Catalysis and Oxidation Reactions
  • Transition Metal Oxide Nanomaterials
  • Conducting polymers and applications
  • Catalytic Processes in Materials Science
  • Advanced biosensing and bioanalysis techniques
  • Electrochemical sensors and biosensors
  • Semiconductor materials and interfaces
  • Advanced Battery Technologies Research
  • Gas Sensing Nanomaterials and Sensors
  • Ga2O3 and related materials
  • Spectroscopy Techniques in Biomedical and Chemical Research
  • Inorganic and Organometallic Chemistry
  • Supercapacitor Materials and Fabrication
  • Porphyrin and Phthalocyanine Chemistry
  • Thermal and Kinetic Analysis
  • ZnO doping and properties
  • Inorganic Chemistry and Materials
  • Oxidative Organic Chemistry Reactions
  • Advanced Battery Materials and Technologies

Central Electrochemical Research Institute
2021-2025

Academy of Scientific and Innovative Research
2021-2025

King Abdullah University of Science and Technology
2018-2022

University of Dayton
1980-1982

Seton Hall University
1980-1982

West Virginia University
1982

Curtiss-Wright (United States)
1981

University of Cincinnati
1980

Indian Institute of Technology Madras
1971-1976

Research in the field of aluminum batteries has focused heavily on electrodes made carbonaceous materials. Still, capacities reported for these multivalent systems remain stubbornly low. It is believed that a high structural quality graphitic carbons and/or specific surface areas >1000 m2 g-1 are key factors to obtain optimal performance and cycling stability. Here an chloride battery presented which reduced graphene oxide (RGO) powder, dried under supercritical conditions, used as active...

10.1002/smll.201803584 article EN Small 2018-10-25

Hydroperoxyl intermediate is a vital component in the mechanism of electrochemical oxygen reduction reaction (ORR) and several other important chemical reactions. The selectivity kinetics ORR are controlled by energetics *OOH (* represents active site). present work integrates iron phthalocyanine (FePc) with sulfonic acid-functionalized multiwalled carbon nanotubes (MWCNTs-SO3H). resulting composite (FePc@MWCNTs-SO3H) demonstrates significantly improved higher four-electron for compared to...

10.1021/acscatal.3c00719 article EN ACS Catalysis 2023-03-13

Achieving on-chip, full-UV-band photodetection across UV-A (315-400 nm), UV-B (280-315 and UV-C (100-280 nm) bands remains challenging due to the limitations in traditional materials, which often have narrow detection ranges require high operating voltages. In this study, we introduce a self-driven, on-chip photodetector based on heterostructure of hybrid gold nanoislands (Au NIs) embedded H-glass cesium bismuth iodide (Cs3Bi2I9). The Au NIs act as catalytic nucleation sites, enhancing...

10.1021/acsnano.4c16106 article EN ACS Nano 2025-02-06

Abstract Organic electrochemical transistors (OECTs) have been widely tested used for biosensing applications due to high sensitivity, low operating potential, better signal-to-noise ratio and operation in aqueous medium. The de-doping OECTs is a diffusion-controlled process which crucially depends on the geometry of channel. This report presents OECT with cylindrical channel its application detection sweat glucose concentration. were fabricated by incorporating PEDOT:PSS-coated single...

10.1186/s40712-025-00267-y article EN cc-by Deleted Journal 2025-04-09

Abstract AVO 3 (A = Ba 2+ , Sr La 3+ Gd ) oxides have been prepared by hydrogen reduction of suitable vanadium(V) ternary oxides. The oxidation state vanadium in the products seems to be controlled nature other cations. In presence strongly basic alkaline‐earth metal ions, and as 2 V O 7 is reduced +4 state. But when A a trivalent lanthanide ion LnVO 4 (Ln or Gd), proceeds +3 yield phases. characterized X‐ray diffraction. BaVO crystallizes hexagonal structure related 8 while SrVO LaVO GdVO...

10.1002/zaac.19754150312 article EN Zeitschrift für anorganische und allgemeine Chemie 1975-07-01

Abstract Flat panel reactors, coated with photocatalytic materials, offer a sustainable approach for the commercial production of hydrogen (H 2 ) zero carbon footprint. Despite this, achieving high solar‐to‐hydrogen (STH) conversion efficiency these reactors is still significant challenge due to low utilization solar light and rapid charge recombination. Herein, hybrid gold nano‐islands (HGNIs) are developed on transparent glass support improve STH efficiency. Plasmonic HGNIs grown an...

10.1002/smll.202401131 article EN cc-by-nc Small 2024-04-02

Long‐time chronoamperometry of electrodes immersed in nonaqueous electrolytes has been employed to investigate the mass transport and charge transfer processes which govern rate alkali metal ion intercalation in. The and, hence, current, appears be controlled by diffusion within . chronoamperometric curves were fit a previously developed model predicts current‐time behavior under control solid‐state diffusion. close agreement this with experimental data allows coefficient other parameters...

10.1149/1.2123951 article EN Journal of The Electrochemical Society 1982-04-01

Abstract Ultraviolet (UV) photodetectors often suffer from the lack of spectral selectivity due to strong interference visible light. In this study, exceptional electrical properties graphene and unique optical carbon nitride thin films (CNTFs) are used design visible‐blind UV photodetectors. First, polycrystalline CNTFs with different thicknesses (12–94 nm) produced by thermal vapor condensation. Compared bulk powder, these have a considerable sp 2 nitrogen deficiency, which is thickness...

10.1002/admi.202200313 article EN Advanced Materials Interfaces 2022-04-27

Metal-free, cost-efficient, redox-active electrode materials, combining graphene derivatives with nitrogen-rich polymelamine (PM), are widely explored as an interface layer for electrocatalysis and electrochemical sensor platform. However, conventional chemical routes often yield of PM suffering from impaired redox behavior, restricting their electron-transfer kinetics. Herein, optimal potentiodynamic method has been established to electrodeposit on electrochemically reduced oxide (ErGO). A...

10.1021/acs.langmuir.3c00128 article EN Langmuir 2023-02-23

Transient potential oscillations in a self-organized system involve sequence of mass-transfer-limited chemical reactions. Often, these determine the microstructure electrodeposited metallic films. In this study, two distinct have been observed during galvanostatic deposition cobalt presence butynediol. Understanding underlying reactions is essential for designing efficient electrodeposition systems. Operando shell-isolated nanoparticle-enhanced Raman spectroscopy deployed to record changes,...

10.1021/acs.jpclett.3c00212 article EN The Journal of Physical Chemistry Letters 2023-03-30

Investigating the behavior of analytes at electrode surface is crucial in understanding electrochemical and electrocatalytic reactions. Although Surface Enhanced Raman Scattering (SERS) sensitive to minor chemical changes analyte, it not widely used study reaction mechanisms on nonplasmonic surfaces because interference from plasmonic SERS substrates. In this study, we have investigated redox Nile Blue A a glassy carbon using pinhole-free silica-coated silver nanoparticles for signal...

10.1021/acs.jpclett.1c01768 article EN The Journal of Physical Chemistry Letters 2021-07-22

10.1016/0022-1902(76)80154-6 article EN Journal of Inorganic and Nuclear Chemistry 1976-01-01
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