A5002478038- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Crystallography and molecular interactions
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystal structures of chemical compounds
- Metal complexes synthesis and properties
- Luminescence and Fluorescent Materials
- Lanthanide and Transition Metal Complexes
- Molecular Sensors and Ion Detection
- Organic Light-Emitting Diodes Research
- Neutrophil, Myeloperoxidase and Oxidative Mechanisms
- Perovskite Materials and Applications
- Polyoxometalates: Synthesis and Applications
- Luminescence Properties of Advanced Materials
- Chemical Synthesis and Characterization
- Nitric Oxide and Endothelin Effects
Tianshui Normal University
2016-2025
Northwest Normal University
2015-2016
Nanjing University
2015
Seven novel coordination polymers derived from the 3-(3′,5′-dicarboxylphenoxy)phthalic acid (H4L) ligand have been constructed under similar synthesized conditions with Co(II), Zn(II), Cd(II) ions in presence of N-donor ancillary ligands, namely, [Co2(HL)(4,4′-bipy)(μ3-OH)(μ2-H2O)]n (1), [Co2(L)(dpa)2]n (2), {[Co2(L)(4,4′-bibp)(H2O)4]·H2O}n (3), [Co2(L)(dib)2]n (4), [Co2(L)(bix)1.5]n (5), [Zn2(L)(bix)1.5]n (6), and {[Cd2(L)(bix)0.5(H2O)]·2H2O}n (7). The various topologies structures...
Seven new complexes based on H4L1 and H4L2, namely, [Cd2(L1)(H2O)5]n (1), {[Cu5(L1)2(μ3-OH)2(H2O)4]·2H2O}n (2), {[Cd2(L1)(4,4′-bipy)2(H2O)3]·2H2O}n (3), [Zn2(L1)(4,4′-bipy)(H2O)3]n (4), {[Ni7(L1)4(4,4′-bipy)12(H2O)12]·2H2O}n (5), {[Ni1.5(L2)(4,4′-bipy)1.5(H2O)4]·H2O}n (6), {[Ni9(L2)6(dib)12(H2O)18]·18H2O}n (7) [(H4L1 = 4-(3′,5′-dicarboxylphenoxy)phthalic acid, H4L2 3-(3′,5′-dicarboxylphenoxy)phthalic 4,4′-bipy 4,4′-bipyridine, dib 1,4-di(1H-imidazol-1-yl)benzene], have been synthesized by...
Two series of lanthanide metal organic frameworks (Ln–MOFs) [Ln(HL)(H2O)3]·H2O and [Ln(HL)(H2O)2] (Ln = Tb, 1; Er, 4; Tm, 5; Yb, 6; Dy, 2; Ho, 3) have been successfully assembled by Ln3+ ions asymmetric polycarboxylate ligand 3-(3′,5′-dicarboxyl-phenoxy) phthalic acid (H4L). The crystal structures, photoluminescence, magnetic properties these compounds investigated. Complexes 1, 4, 5, 6 are isostructural show 2D layer constructed hydrogen bonding interactions between the coordination water...
Two 3D/2D anionic metal–organic frameworks (MOFs), [Cu(HL)]n (1) and [Mn3(L)2(DMF)4]n (2) (DMF = N,N-dimethylformamide), were synthesized by the solvothermal reaction of metal salts 5′-(4-carboxyphenyl)-2′,4′,6′-triethyl-[1,1':3′,1″-terphenyl]-4,4″-dicarboxylic acid (H3L). Single-crystal X-ray diffraction analyses revealed that complex 1 shows three-dimensional (3D) with a (3,6)-connected 3-fold interpenetrated topology Schläfli symbols {4.62}2{42.610.83}, whereas two-dimensional (2D)...
Seven new metal–organic frameworks (MOFs), namely, [Zn 2 ( L 1 )(H O) 3 ] n ), )(dib)(H {[Zn )(4,4′-bipy)(H ]·H O} [Cd )(1,10-phen)] 4 [Ni (H )(4,4′-bipy)(μ -OH)(μ -H O)] 5 {[Co )(4,4′-bibp) ]·(4,4′-bibp) } 6 and [Co 7 where H are semi-rigid 3-(3,5-dicarboxylphenoxy)phthalic acid 4-(3,5-dicarboxylphenoxy)phthalic acid, respectively, 4,4′-bipy is 4,4′-bipyridine, dib 1,4-bis(1 -imidazol-1-yl)benzene, 1,10-phen 1,10-phenanthroline 4,4′-bipb 1,4-bis(pyridin-4-yl)benzene, have been prepared...
Hypochlorous acid (HOCl) is widely used in daily production and life because of its green strongly oxidizing properties. Additionally, as a vital reactive oxygen species (ROS), it an innate immune system weapon performs critical function many pathophysiology processes. In this paper, novel water-soluble fluorescent probe, BMH, with excellent performance designed synthesized by simple condensation benzocoumarin 2-mercaptoethanol. BMH has specific selectivity, sensitivity, ultra-fast response...
Abstract A novel 1D Zinc compound, formulated as [Zn(H 2 L 2− )(H O)] n ( 1 ) (H 4 = 3‐(3′,5′‐dicarboxyphenyl)pyridine‐2,6‐dicarboxylic acid), is synthesized by a rigid organic multi‐carboxylic acid ligand under hydrothermal conditions. Compound crystallizes in the orthorhombic P space group and exhibits fishbone‐like chain, exhibiting strong blue fluorescence emission at room temperature upon excitation. Fluorescence titration shows that intensity of compound varied contacting with...
Two coordination polymers (CPs), namely, [Mn3(L)2(4,4'-bipy)2(H2O)2]n (1) and [Ni(L1)(1,4-bib)(H2O)]n (2) (H3L = 5-(3-bromo-4-carboxyphenoxy)isophthalic acid, H2L1 5-(3-hydroxyphenoxy)isophthalic 4,4'-bpy 4,4'-bipyridine, 1,4-bib 1,4-bis(1H-imidazol-1-yl)benzene), were synthesized under hydrothermal conditions. Most notably, with the help of bromine atom-inducing effect, ligand transformation was observed in structure complex 2, which scrutinized thoroughly by single crystal X-ray...