A5101597515- Metal-Organic Frameworks: Synthesis and Applications
- Nanomaterials for catalytic reactions
- Covalent Organic Framework Applications
- Advanced Photocatalysis Techniques
- Supercapacitor Materials and Fabrication
- Electrocatalysts for Energy Conversion
- Catalytic Processes in Materials Science
- CO2 Reduction Techniques and Catalysts
- Ionic liquids properties and applications
- Extraction and Separation Processes
- Advancements in Battery Materials
- Advanced Nanomaterials in Catalysis
- Adsorption and biosorption for pollutant removal
- Gas Sensing Nanomaterials and Sensors
- Carbon Dioxide Capture Technologies
- Advanced battery technologies research
- Luminescence and Fluorescent Materials
- Catalysis for Biomass Conversion
- Nanocluster Synthesis and Applications
- Luminescence Properties of Advanced Materials
- Aerogels and thermal insulation
- Radioactive element chemistry and processing
- Flame retardant materials and properties
- Carbon dioxide utilization in catalysis
- Supramolecular Chemistry and Complexes
Xiamen University
2020-2025
Hebei University of Technology
2023
Shandong Academy of Sciences
2021
Qilu University of Technology
2021
École Polytechnique Fédérale de Lausanne
2015-2020
Xiamen University of Technology
2016-2020
Government of the Republic of Korea
2018
Hanyang University
2018
HES-SO Valais-Wallis
2015-2016
Huaqiao University
2016
Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) of 1020 m(2) g(-1). Using poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) shell source N, P, S-doping source, the ZIF-67 core structural template well extra N-doping NPS-HCS were obtained superhydrophilicity. All these features render...
Metal-organic frameworks (MOFs) offer great promise in a variety of gas- and liquid-phase separations. However, the excellent performance on lab scale hardly translates into pilot- or industrial-scale applications due to microcrystalline nature MOFs. Therefore, structuring MOFs pellets beads is highly solicited timely requirement. In this work, general method developed for preparing MOF-polymer composite based an easy polymerization strategy. This adopts biocompatible, biodegradable...
Abstract Electrocatalytic reduction of carbon monoxide into fuels or chemicals with two more carbons is very attractive due to their high energy density and economic value. Herein we demonstrate the synthesis a hydrophobic Cu/Cu 2 O sheet catalyst n-butylamine layer its application in CO electroreduction. The on this produces products Faradaic efficiency 93.5% partial current 151 mA cm −2 at potential −0.70 V versus reversible hydrogen electrode. A 68.8% 111 for ethanol were reached, which...
With the fast-growing accumulation of electronic waste and rising demand for rare metals, it is compelling to develop technologies that can promotionally recover targeted like gold, from waste, a process referred as urban mining. Thus, there increasing interest in design materials achieve rapid, selective gold capture while maintaining high adsorption capacity, especially complex aqueous-based matrices. Here, highly porous metal-organic framework (MOF)–polymer composite, BUT-33–poly( para...
Recently, many approaches were applied for assembling graphene sheets into a three-dimensional structure. However, it is still great challenge to obtain macroporous network with high mechanical strength after drying. Herein, an ammonia strengthened aerogel was prepared. Based on chemistry and ice physics, the of improved greatly when hydrogel treated by solution at ambient temperature. The results demonstrated that structure aerogels destroyed thoroughly without treatment; conversely,...
3D hierarchical flowerlike MgO hollow spheres with extremely high surface area showed excellent adsorption properties for heavy metal ions and catalytic the Claisen–Schmidt condensation reaction.
Nitrogen-rich carbon nanosheets derived from petroleum coke with g-C<sub>3</sub>N<sub>4</sub> as a self-decomposed template and nitrogen dopant show ultrahigh lithium/potassium storage capabilities.
Abstract Electrochemical oxidation of biomass‐derived 5‐hydroxymethylfurfural (HMF) provides an environmentally friendly route for producing the sustainable polymer monomer 2,5‐furandicarboxylic acid (FDCA). Thus, precisely adjusting synergistic adsorption among key reactive species, such as HMF and OH ads , on carefully designed catalyst surface is essential achieving satisfactory catalytic performance to FDCA it closely related strength configuration reaction substrates. This kind...
Transition-metal phosphides have received tremendous attention during the past few years because they are earth-abundant, cost-effective, and show outstanding catalytic performance in several electrochemically driven conversions including hydrogen evolution, oxygen water splitting. As one member of transition-metal phosphides, Cox P-based materials been widely explored as electrocatalyts; however, their application traditional thermal catalysis rarely reported. In this work, cobalt...
Abstract Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) of 1020 m 2 g −1 . Using poly(cyclotriphosphazene‐ co ‐4,4′‐sulfonyldiphenol) (PZS) shell source N, P, S‐doping source, the ZIF‐67 core structural template well extra N‐doping NPS‐HCS were obtained superhydrophilicity. All these features...
Abstract MOF‐derived Co 3 S 4 /CN hollow nanoboxes (CN=nitrogen‐doped carbon) was used to catalyze the chemoselective reduction of nitroarenes anilines under mild reaction conditions with H 2 as reducing agent. The catalyst provides high conversion efficiencies and selectivities for a variety nitroarene substrates that contain electron‐donating or electron‐withdrawing substituents (in methanol at 60 °C). Further, nanobox inhibits both dehalogenation vinyl hydrogenation reactions, which are...
A new type lead-free catalyst of a Pd-Cu2O nanocomposite was developed for highly selective semi-hydrogenation alkynes. With unprecedented selectivity the terminal alkynes to alkenes, we show first time that only hydrogenated alkynes, i.e. did not hydrogenate internal
A metal–organic framework/polymer derived catalyst containing single-atom nickel species shows good performance for electroreduction of CO<sub>2</sub> to CO.
The Cu precursor diffused into UiO-66 by the double solvent method is reduced NaBH<sub>4</sub> to form nanoparticles. After introducing Zn<sup>2+</sup>, Cu/ZnO<sub>x</sub>@UiO-66 H<sub>2</sub> synthesized, which catalyzes hydrogenation of CO<sub>2</sub> methanol efficiently.
Recycling gold from electronic waste represents a sustainable and environmentally friendly strategy for both resource recovery reduction. In this study, we designed an innovative highly stable porous aromatic framework (PAF)/polymer composite, PAF‐147/polydopamine (PDA), as efficient adsorbent selective the first time. The maximum adsorption capacity of PAF‐147/PDA reached 1700 mg·g⁻¹. Furthermore, it could rapidly extract over 95% solutions in pH range 0‐10 within just 2 minutes....
A polymer containing N, P and S could be coated on various substrates, the derived P, S-doped hollow carbon shells display good performance for selective oxidation of carbon–hydrogen bonds.
The traditional vacuum activation of covalent organic framework (COF) materials typically erodes the materials' crystallinity significantly and then reduces surface area isolated materials. Developing new methods for synthesizing robust COFs which could survive duration process is great practical significance. In this work, a imine-linked 2D COF TAPB-TA was creatively constructed in supercritical CO2 (ScCO2) with γ-valerolactone (GVL) as cosolvent instead previously widely reported reaction...
Due to their high structural tunability, remarkable internal surface areas, readily accessible pore space, and host of possible applications, covalent organic frameworks (COFs) remain at the forefront materials science research. Unfortunately, many COFs suffer from distortions or collapse during activation, which can lead a substantial loss crystallinity functionality. Thus, herein, we demonstrate facile method address this issue by introducing polymer guests. The adheres COF wall, acting as...
A new type of spindle-shaped nanoscale yolk/shell magnetic stirring bar containing noble metal nanoparticles was prepared. The as-synthesized Pd-Fe@meso-SiO2 not only showed impressive activity and stability as a heterogeneous catalyst in macroscopic flask system, but also acted an efficient stir microscopic droplet system.