A5015123508- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
- Advanced Thermodynamics and Statistical Mechanics
- Quantum and electron transport phenomena
- Molecular Junctions and Nanostructures
- Porphyrin and Phthalocyanine Chemistry
- Metal-Catalyzed Oxygenation Mechanisms
- Quantum, superfluid, helium dynamics
- Electron Spin Resonance Studies
- Metal complexes synthesis and properties
Universitat de València
2022-2023
Parc Científic de la Universitat de València
2022-2023
Abstract Hybrid devices based on spin‐crossover (SCO)/2D heterostructures grant a highly sensitive platform to detect the spin transition in molecular SCO component and tune properties of 2D material. However, fragility materials upon thermal treatment, light irradiation, or contact with surfaces methodologies used for their processing have limited applicability. Here, an easily processable robust SCO/2D hybrid device outstanding performance sublimable [Fe(Pyrz) 2 ] molecule deposited over...
Recent theory and experiments have showcased how to harness quantum mechanics assemble heat/information engines with efficiencies that surpass the classical Carnot limit. So far, this has required atomic are driven by cumbersome external electromagnetic sources. Here, using molecular spintronics, an implementation is both electronic autonomous proposed. The spintronic engine heuristically deploys several known assets having a chain of spin qubits formed paramagnetic Co center phthalocyanine...
Chemical design of complexes with thermal- and light-induced spin switching integration as thin films in graphene-based devices by sublimation.
Materials based on spin crossover (SCO) molecules have centered the attention in molecular magnetism for more than 40 years as they provide unique examples of multifunctional and stimuli-responsive materials, which can be then integrated into electronic devices to exploit their bistability. This process often requires preparation thermally stable SCO that sublime remain intact contact with surfaces. However, number robust sublimable is still very scarce. Here, we report a novel example this...
Materials based on spin crossover (SCO) molecules have centered the attention in molecular magnetism for more than 40 years as they provide unique examples of multifunctional and stimuli-responsive materials, which can be then integrated into electronic devices to exploit their bistability. This process often requires preparation thermally stable SCO that sublime remain intact contact with surfaces. However, number robust sublimable is still very scarce. Here, we report a novel example this...
Recent theory and experiments have showcased how to harness quantum mechanics assemble heat/information engines with efficiencies that surpass the classical Carnot limit. So far, this has required atomic are driven by cumbersome external electromagnetic sources. Here, using molecular spintronics, we propose an implementation is both electronic autonomous. Our spintronic engine heuristically deploys several known assets having a chain of spin qubits formed paramagnetic Co centers...
Among the different types of switchable molecular compounds, sublimable Fe(II) SCO molecules provide a suitable platform to develop smart devices that respond external stimuli. Here we report synthesis, crystallographic structure and magnetic properties three new neutral belonging {Fe[H2B(pz)2]2(L)} family with bidentate-alpha-diimine ligands L = 3-(pyridin-2-yl)-[1,2,3]triazolo[1,5-a]pyridine (tzpy), 5,5,6,6-tetrahydro-4H,4H-2,2-bi(1,3-thiazine) (btz) 4,4,5,5-tetrahydro-2,2-bithiazole (bt)...