A5001461226- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Ammonia Synthesis and Nitrogen Reduction
- Metal-Organic Frameworks: Synthesis and Applications
- Crystallography and molecular interactions
- Electrocatalysts for Energy Conversion
- Catalytic Processes in Materials Science
- Chemical Synthesis and Reactions
- Polyoxometalates: Synthesis and Applications
- Metal complexes synthesis and properties
- Electrochemical sensors and biosensors
- Chemical Reactions and Mechanisms
- Fuel Cells and Related Materials
- Advanced battery technologies research
- Industrial Gas Emission Control
- Electrochemical Analysis and Applications
- Fluorine in Organic Chemistry
University of Zurich
2023-2024
Western Washington University
2018-2021
Bellingham Technical College
2020
Metal complexes composed of redox-active pyridinediimine (PDI) ligands are capable forming ligand-centered radicals. In this Forum article, we demonstrate that integration these types sites with bioinspired secondary coordination sphere motifs produce direduced complexes, where the reduction potential ligand-based redox is uncoupled from sphere. The utility such ligand design was explored by encapsulating redox-inactive Lewis acidic cations via installation a pendant benzo-15-crown-5 in...
The reduction of nitrogen oxides (NxOyn-) to dinitrogen gas by samarium(ii) iodide is reported. polyoxoanions nitrate (NO3-) and nitrite (NO2-), as well nitrous oxide (N2O) nitric (NO) were all shown react with stoichiometric amounts SmI2 in THF for the complete denitrification N2.
Selective coupling of NO by a nonclassical dinuclear dinitrosyliron complex (D-DNIC) to form N2O is reported. The facilitated the pyridinediimine (PDI) ligand scaffold, which enables necessary denticity changes produce mixed-valent, electron-deficient tethered DNICs. One-electron oxidation [{Fe(NO)2}]210/10 Fe2(PyrrPDI)(NO)4 (4) results in via mixed-valent {[Fe(NO)2]2}9/10 species, possesses an four-coordinate {Fe(NO)2}10 site, crucial N-N bond formation. hemilability PDI scaffold dictates...